AuP(C₆H₅)3CNO

Base Information

Chemical Name:AuP(C₆H₅)3CNO
CAS No.:98875-32-2
Molecular Formula:C₁₉H₁₅AuNOP
Molecular Weight:501.274
Hs Code.:

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Chemical Property of AuP(C₆H₅)3CNO

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Technology Process of AuP(C₆H₅)3CNO

There total 2 articles about AuP(C₆H₅)3CNO which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 98875-33-3,14853-96-4
bis(triphenylphosphine)gold(I) nitrate

: 98875-34-4
Na⁽¹⁺⁾*[Au(CNO)2]^(1-)=Na[Au(CNO)2]

: 98875-32-2
AuP(C₆H₅)3CNO

Guidance literature:: In N,N-dimethyl-formamide; dissolving Na(Au(CNO)2) in DMF; adding slowly soln. of Au(P(C6H5)3)2NO3in DMF with stirring; mechanism discussed;; addn. of H2O; filtration; recrystn. by slow diffusion of hexane into CH2Cl2 soln.; elem. anal.;;

Reference yield: 38.0%

: 14897-32-6
(triphenylphosphine)gold(I) nitrate

: 98875-32-2
AuP(C₆H₅)3CNO

Guidance literature:: With CO; AgNO₃; CH₂Cl₂; In dichloromethane; byproducts: AgCl, AuP(C6H5)3Cl; further reagent: traces of H2O; passing CO through soln. of Au complex in CH2Cl2; sealing vessel; stirring for 1 h; treating with 2 equiv. AgNO3 in methanol; filtration; redissolving of crude mixt. in CH2Cl2; passing CO through soln. in 4 cycles;; filtering off over silca gel with diethyl ether; chromatography over silica gel column with toluene for the eluation of AuP(C6H5)3Cl followed by (C2H5)2O to recover AuP(C6H5)3CNO; recrystn. by slow diffusion of hexane into CH2Cl2 soln.; elem. anal.;;

Reference yield: 41.0%

: Au₈⁽²⁺⁾*7(P(C₆H₅)3)*2NO₃^(1-) = Au₈(P(C₆H₅)3)7(NO₃)2

: 98875-32-2
AuP(C₆H₅)3CNO

: 98921-33-6
Au₁₁⁽³⁺⁾*8P(C₆H₅)3*2CNO^(1-)*NO₃^(1-)=Au₁₁(P(C₆H₅)3)8(CNO)2NO₃

Guidance literature:: In dichloromethane; dissolving Au cluster and AuP(C6H5)3CNO in CH2Cl2; storage for 2 weeks in the dark;; chromatography on Sephadex column with acetone; recrystn. by slow diffusion of hexane into CH2Cl2 soln.; elem. anal.;;