RhCl(1,4-cyclooctadiene)PCy₃

Base Information

Chemical Name:RhCl(1,4-cyclooctadiene)PCy₃
CAS No.:65394-49-2
Molecular Formula:C₂₆H₄₅ClPRh
Molecular Weight:526.976
Hs Code.:

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Chemical Property of RhCl(1,4-cyclooctadiene)PCy₃

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Technology Process of RhCl(1,4-cyclooctadiene)PCy₃

There total 1 articles about RhCl(1,4-cyclooctadiene)PCy₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: chloro(1,5-cyclooctadiene)rhodium(I) dimer

: 2622-14-2
tricyclohexylphosphine

: 65394-49-2
RhCl(1,4-cyclooctadiene)PCy₃

Guidance literature:: In benzene; under N2 atm. (Rh(cod)(μ-Cl))2 and PCy3 in benzene was stirred for 2 h; soln. was concd., pentane was added, ppt. was dried in vacuo for 3 h; elem. anal.;
DOI:10.1139/v03-145

Reference yield: 90.0%

: 65394-49-2
RhCl(1,4-cyclooctadiene)PCy₃

: sodium tris(tert-butoxy)silanolate

: 681485-48-3
[Rh(cod)(PCy₃)(OSi(O-t-Bu)3)]

Guidance literature:: In benzene; under Ar atm. (Rh(cod)(PCy3)(Cl)) and NaOSi(O-t-Bu)3 in benzene were stirred at room temp. for 24 h; soln. was concd., pentane was added, soln. was filtered and evapd.; elem. anal.;
DOI:10.1139/v03-145

Reference yield: 85.0%

: NaOSi-i-Pr₃

: 65394-49-2
RhCl(1,4-cyclooctadiene)PCy₃

: 681485-47-2
[Rh(cod)(PCy₃)(OSi-i-Pr₃)]

Guidance literature:: In benzene; under Ar atm. (Rh(cod)(PCy3)(Cl)) and NaOSi-i-Pr3 in benzene were stirred at room temp. for 24 h; soln. was concd., pentane was added, soln. was filtered and evapd.; elem. anal.;
DOI:10.1139/v03-145