RuClBr₂(NS)(AsPh₃)2

Base Information

Chemical Name:RuClBr₂(NS)(AsPh₃)2
CAS No.:88118-46-1
Molecular Formula:C₃₆H₃₀As₂Br₂ClNRuS
Molecular Weight:954.881
Hs Code.:

RuClBr<sub>2</sub>(NS)(AsPh<sub>3</sub>)2

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of RuClBr₂(NS)(AsPh₃)2

Chemical Property:

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Technology Process of RuClBr₂(NS)(AsPh₃)2

There total 1 articles about RuClBr₂(NS)(AsPh₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 105454-00-0,105453-99-4,5964-00-1
trithiazyl trichloride

: 50492-96-1
RuBr₃(AsPh₃)2*MeOH

: 603-32-7
triphenyl-arsane

: 88118-46-1
RuClBr₂(NS)(AsPh₃)2

Guidance literature:: In tetrahydrofuran; dichloromethane; byproducts: triphenylarsine sulfide; THF-soln. of (NSCl)3 was added to a soln. of Ru-compd. in CH2Cl2 followed by vigorous stirring for 30 min; the resulting soln. was heated on a water bath for about 10 min to remove CH2Cl2, then AsPh3 was added;; the product was collected, washed with MeOH and ether; recrystn. by dissolving in boiling CH2Cl2, evapg. the soln. to small vol. and addn. of hot MeOH; the compd. was sepd., washed and dried in vacuo at room temp.; elem.anal.;;
DOI:10.1016/S0020-1693(00)81426-7

Reference yield:

: 88118-46-1
RuClBr₂(NS)(AsPh₃)2

: 603-32-7
triphenyl-arsane

: {ruthenium(nitrosyl)Br₃(trophenylarsine)2

Guidance literature:: With nitrosyl bromide; In dichloromethane; CH2Cl2-soln. of NOBr was added dropwise to a CH2Cl2-soln. of Ru-compd. and the mixt. was stirred for about 30 min, followed by addn. of MeOH; the resulting soln. was heated on a water bath for 10 min and AsPh3 was added;; the product was sepd., washed with MeOH and ether and recrystd. by dissolving in boiling CH2Cl2, evapg. the soln. to small vol., and adding of hot MeOH; elem.anal.;;
DOI:10.1016/S0020-1693(00)81426-7

Reference yield:

: 88118-46-1
RuClBr₂(NS)(AsPh₃)2

: 603-32-7
triphenyl-arsane

: {ruthenium(II)nitrosyl Br₂Cl(triphenylarsine)2}

Guidance literature:: With nitrosylchloride; In dichloromethane; a satd. soln. of NOCl in CH2Cl2 was added to CH2Cl2-soln. of Ru-compd. followed by stirring for 30 min, then AsPh3 was added followed by addn. of MeOH, refluxing for 5 min;; the product was centrifuged, washed with MeOH and ether, and dried in vacuo; elem.anal.;;
DOI:10.1016/S0020-1693(00)81426-7