[(S)-9-(tert-Butyl-diphenyl-silanyloxy)-4-isopropenyl-11-methoxymethoxy-1,11-dimethyl-2,14-dioxo-tetradeca-7,12-diynyl]-phosphonic acid dimethyl ester

Base Information

Chemical Name:[(S)-9-(tert-Butyl-diphenyl-silanyloxy)-4-isopropenyl-11-methoxymethoxy-1,11-dimethyl-2,14-dioxo-tetradeca-7,12-diynyl]-phosphonic acid dimethyl ester
CAS No.:191214-02-5
Molecular Formula:C₃₉H₅₃O₈PSi
Molecular Weight:708.904
Hs Code.:

[(S)-9-(tert-Butyl-diphenyl-silanyloxy)-4-isopropenyl-11-methoxymethoxy-1,11-dimethyl-2,14-dioxo-tetradeca-7,12-diynyl]-phosphonic acid dimethyl ester

Synonyms:

Suppliers and Price of [(S)-9-(tert-Butyl-diphenyl-silanyloxy)-4-isopropenyl-11-methoxymethoxy-1,11-dimethyl-2,14-dioxo-tetradeca-7,12-diynyl]-phosphonic acid dimethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [(S)-9-(tert-Butyl-diphenyl-silanyloxy)-4-isopropenyl-11-methoxymethoxy-1,11-dimethyl-2,14-dioxo-tetradeca-7,12-diynyl]-phosphonic acid dimethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [(S)-9-(tert-Butyl-diphenyl-silanyloxy)-4-isopropenyl-11-methoxymethoxy-1,11-dimethyl-2,14-dioxo-tetradeca-7,12-diynyl]-phosphonic acid dimethyl ester

There total 13 articles about [(S)-9-(tert-Butyl-diphenyl-silanyloxy)-4-isopropenyl-11-methoxymethoxy-1,11-dimethyl-2,14-dioxo-tetradeca-7,12-diynyl]-phosphonic acid dimethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 536-59-4,18457-55-1
(-)-perillyl alcohol

: 191214-02-5
[(S)-9-(tert-Butyl-diphenyl-silanyloxy)-4-isopropenyl-11-methoxymethoxy-1,11-dimethyl-2,14-dioxo-tetradeca-7,12-diynyl]-phosphonic acid dimethyl ester

Guidance literature:: Multi-step reaction with 12 steps

1: 99 percent / VO(acac)2, t-BuOOH / CH₂Cl₂; decane / 0 - 20 °C

2: periodic acid / tetrahydrofuran; H₂O / 0 - 20 °C

3: p-TsOH

5: PPh₃

6: 1.) n-BuLi

7: imidazole / dimethylformamide

8: p-TsOH / H₂O

9: pyridinium dichromate

10: BuLi

11: 88 percent / 2,3-dichloro-5,6-dicyano-1,4-benzoquinone / H₂O

12: 1.) oxalyl chloride, DMSO, 2.) triethylamine

With 1H-imidazole; tert.-butylhydroperoxide; dipyridinium dichromate; n-butyllithium; oxalyl dichloride; bis(acetylacetonate)oxovanadium; toluene-4-sulfonic acid; dimethyl sulfoxide; periodic acid; triethylamine; triphenylphosphine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; decane; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1021/jo970360d

Reference yield:

: 190718-78-6
((4S)-4-(prop-1-en-2-yl)-7-oxabicyclo[4.1.0]heptan-1-yl)methanol

: 191214-02-5
[(S)-9-(tert-Butyl-diphenyl-silanyloxy)-4-isopropenyl-11-methoxymethoxy-1,11-dimethyl-2,14-dioxo-tetradeca-7,12-diynyl]-phosphonic acid dimethyl ester

Guidance literature:: Multi-step reaction with 11 steps

1: periodic acid / tetrahydrofuran; H₂O / 0 - 20 °C

2: p-TsOH

4: PPh₃

5: 1.) n-BuLi

6: imidazole / dimethylformamide

7: p-TsOH / H₂O

8: pyridinium dichromate

9: BuLi

10: 88 percent / 2,3-dichloro-5,6-dicyano-1,4-benzoquinone / H₂O

11: 1.) oxalyl chloride, DMSO, 2.) triethylamine

With 1H-imidazole; dipyridinium dichromate; n-butyllithium; oxalyl dichloride; toluene-4-sulfonic acid; dimethyl sulfoxide; periodic acid; triethylamine; triphenylphosphine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; water; N,N-dimethyl-formamide;
DOI:10.1021/jo970360d

Reference yield:

: 190718-43-5
(S)-7,7-dimethoxy-5-isopropenyl-1-heptyne

: 191214-02-5
[(S)-9-(tert-Butyl-diphenyl-silanyloxy)-4-isopropenyl-11-methoxymethoxy-1,11-dimethyl-2,14-dioxo-tetradeca-7,12-diynyl]-phosphonic acid dimethyl ester

Guidance literature:: Multi-step reaction with 7 steps

1: 1.) n-BuLi

2: imidazole / dimethylformamide

3: p-TsOH / H₂O

4: pyridinium dichromate

5: BuLi

6: 88 percent / 2,3-dichloro-5,6-dicyano-1,4-benzoquinone / H₂O

7: 1.) oxalyl chloride, DMSO, 2.) triethylamine

With 1H-imidazole; dipyridinium dichromate; n-butyllithium; oxalyl dichloride; toluene-4-sulfonic acid; dimethyl sulfoxide; triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In water; N,N-dimethyl-formamide;
DOI:10.1021/jo970360d