(η-5-((1R,2R,5R)-5-methyl-2-(2-phenyl-2-propyl)cyclohex-1-yl)cyclopentadienyl)dicarbonylcobalt

Base Information

Chemical Name:(η-5-((1R,2R,5R)-5-methyl-2-(2-phenyl-2-propyl)cyclohex-1-yl)cyclopentadienyl)dicarbonylcobalt
CAS No.:112505-34-7
Molecular Formula:C₂₃H₂₇CoO₂
Molecular Weight:394.459
Hs Code.:

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Chemical Property of (η-5-((1R,2R,5R)-5-methyl-2-(2-phenyl-2-propyl)cyclohex-1-yl)cyclopentadienyl)dicarbonylcobalt

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Technology Process of (η-5-((1R,2R,5R)-5-methyl-2-(2-phenyl-2-propyl)cyclohex-1-yl)cyclopentadienyl)dicarbonylcobalt

There total 1 articles about (η-5-((1R,2R,5R)-5-methyl-2-(2-phenyl-2-propyl)cyclohex-1-yl)cyclopentadienyl)dicarbonylcobalt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 15226-74-1,61091-28-9,61117-58-6
dicobalt octacarbonyl

: 112505-23-4
(1R,2R,5R)-1-cyclopentadienyl-5-methyl-2-(2-phenyl-2-propyl)cyclohexane

: 112505-34-7
(η-5-((1R,2R,5R)-5-methyl-2-(2-phenyl-2-propyl)cyclohex-1-yl)cyclopentadienyl)dicarbonylcobalt

Guidance literature:: In 1,2-dichloro-ethane; cyclohexene; A soln. of the cyclohexane in CH2Cl2/cyclohexene is degassed and added to Co2(CO)8. Mixt. is heated to reflux under N2 for 16 h.; Evapn., resulting oil is taken up in pentane, column chromy. (alumina, pentane) resulting in a red oil.;
DOI:10.1021/om00094a015

Reference yield: 87.3%

: 112505-34-7
(η-5-((1R,2R,5R)-5-methyl-2-(2-phenyl-2-propyl)cyclohex-1-yl)cyclopentadienyl)dicarbonylcobalt

: 74585-57-2
13-(trimethylsilyl)-1-tridecene-6,12-diyne

: (η-5-((1R,2R,5R)-5-methyl-2-(2-phenyl-2-propyl)cyclohex-1-yl)cyclopentadienyl)cobalt{(CH2)4C6H3(CH2)3(trimethylsilyl)}

Guidance literature:: In toluene; Irradiation (UV/VIS); Addn. of degassed soln. of cobalt complex to diyne under N2, heating to reflux, irradiation by projector lamp (250 W) for 10 h.; Evapn., filtration through alumina with pentane to provide inseparable mixt. of two isomers.;
DOI:10.1021/om00094a015

Reference yield: 73.6%

: 112505-34-7
(η-5-((1R,2R,5R)-5-methyl-2-(2-phenyl-2-propyl)cyclohex-1-yl)cyclopentadienyl)dicarbonylcobalt

: 112505-32-5
1-(Trimethylsilyl)-1,7-decadiyne

: (η5-{(1R,2R,5R)-5-methyl-2-(2-phenyl-2-propyl)cyclohex-1-yl}cyclopentadienyl)cobalt{(CH2)4C2C(trimethylsilyl)C(O)C(ethyl)}

Guidance literature:: In tetrahydrofuran; Irradiation (UV/VIS); Degassed THF soln. of diyne and cobalt complex is irradiated at -20°C (450-W Hanovia mercury lamp) for 6 h.; Flash chromy., elution of arene byproducts with ether, elution with MeOH/ether yields 60:40 mixt. of diastereomeric complexes which are separable by flash chromy., elem. anal.;
DOI:10.1021/om00094a015