Cp(CO)Ru(PPh₃)C(O)(C₆H₄-p-CH₃)

Base Information

• Chemical Name: Cp(CO)Ru(PPh₃)C(O)(C₆H₄-p-CH₃)
• CAS No.: 117040-93-4
• Molecular Formula: C₃₂H₂₇O₂PRu
• Molecular Weight: 575.609
• Mol file: 117040-93-4.mol

Synonyms:

Chemical Property of Cp(CO)Ru(PPh₃)C(O)(C₆H₄-p-CH₃)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Cp(CO)Ru(PPh₃)C(O)(C₆H₄-p-CH₃)

There total 1 articles about Cp(CO)Ru(PPh₃)C(O)(C₆H₄-p-CH₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

(C5H5)(CO)2Ru(P(C6H5)3)(1+)*PF6(1-)=(C5H5)(CO)2Ru(P(C6H5)3)PF6 (91482-99-4) + para-methylphenylmagnesium bromide (4294-57-9) → Cp(CO)Ru(PPh3)C(O)(C6H4-p-CH3) (117040-93-4)

Guidance literature:

With water; In tetrahydrofuran; under N2; CpRu(CO)2(PPh3)(1+)*PF6(1-) in THF stirred at -78°C; addn. of 2 equiv. CH3C5H4MgBr ether soln.; allowed to warm slowly and addn. of some drops of water;; evapn.; chromd. (Al2O3, hexane/ethyl acetate); evapn.;

DOI:10.1021/om00103a016

Reference yield: 20.0%

Cp(CO)Ru(PPh3)C(O)(C6H4-p-CH3) (117040-93-4) + trimethoxonium tetrafluoroborate (420-37-1) → Cp(CO)Ru(PPh3)CH(OCH3)(C6H4-p-CH3)

Guidance literature:

With sodium tetrahydroborate; sodium methylate; In methanol; dichloromethane; Cp(CO)(PPh3)RuCOCH3C6H4, 2-3 equiv. (CH3)3O(1+)BF4(1-) stirred (N2) in CH2Cl2 (24h); addn. of this soln. of Cp(CO)(PPh3)Ru=C(OCH3)CH3C6H4(1+) to soln. of 2 equiv. NaBH4 and 4equiv. NaOCH3 in CH3OH at -80°C; stirred 15 min; poured in aq. K2CO3; extn. (CH2Cl2); dried (K2CO3), concn.; chromd.; recrystn. hexane soln. gave crystals; isomer ratio 10:1;

DOI:10.1021/om00103a016

upstream raw materials:

(C₅H₅)(CO)2Ru(P(C₆H₅)3)⁽¹⁺⁾*PF₆^(1-)=(C₅H₅)(CO)2Ru(P(C₆H₅)3)PF₆

para-methylphenylmagnesium bromide