(R)-acetyl(carbonyl)(η5-cyclopentadienyl)(tri-p-tolylphosphine)iron

Base Information

Chemical Name:(R)-acetyl(carbonyl)(η5-cyclopentadienyl)(tri-p-tolylphosphine)iron
CAS No.:117228-04-3
Molecular Formula:C₂₉H₂₉FeO₂P
Molecular Weight:496.369
Hs Code.:

Synonyms:

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Chemical Property of (R)-acetyl(carbonyl)(η5-cyclopentadienyl)(tri-p-tolylphosphine)iron

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Technology Process of (R)-acetyl(carbonyl)(η5-cyclopentadienyl)(tri-p-tolylphosphine)iron

There total 1 articles about (R)-acetyl(carbonyl)(η5-cyclopentadienyl)(tri-p-tolylphosphine)iron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 117228-66-7
(η-Cp)Fe{PMePh3}(CO)(Me)

: 117228-04-3
(η-Cp)(CO)(COMe)Fe(P(p-MeC6H4)3)

Guidance literature:: With carbon monoxide; In acetonitrile; Electrochem. Process; carbonylation reaction in CH3CN (0.1 M tetrabutylammonium hexafluorophosphate) under 1 atm CO at 0°C using voltammetry (acetyl-ferrocene/ferrocenium couple); Kinetics;

Reference yield: 41.0%

: 117228-04-3
(η-Cp)(CO)(COMe)Fe(P(p-MeC6H4)3)

: 464-49-3,68546-28-1
(1R)-1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one

: (S(Fe),1R,2S,4R)-carbonyl(η5-cyclopentadienyl)[(2-hydroxy-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl)acetyl](tri-p-tolylphosphine)iron

: (R(Fe),1R,2S,4R)-carbonyl(η5-cyclopentadienyl)[(2-hydroxy-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl)acetyl](tri-p-tolylphosphine)iron

Guidance literature:: With butyllithium; methanol; In tetrahydrofuran; hexane; (N2); hexanic BuLi (1.38 mmol) soln. added to THF soln. of Fe compd. (1.12 mmol) at -78 °C; resulting dark-red soln. stirred for 30 min;THF soln. of the camphor (1.51 mmol) added; stirring at -78 °C for 90 min; react. mechanism discussed; quenching (excess CH3OH); warming (room temp.); evapn. (vac.); ether added; filtration (silica); filtrate column chromd. (SiO2, EtOAc/light petroleum) giving S/R(Fe) compd. mixt. (30/1, 1H NMR); recrystn. (ether/pentane) gave S(Fe) compd.; elem. anal.;

Reference yield: 12.0%

: 156928-55-1,117228-04-3,156928-56-2
(R)-acetyl(carbonyl)(η5-cyclopentadienyl)(tri-p-tolylphosphine)iron

: 464-49-3,68546-28-1
(1R)-1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one

: (R(Fe),1R,2S,4R)-carbonyl(η5-cyclopentadienyl)[(2-hydroxy-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl)acetyl](tri-p-tolylphosphine)iron

Guidance literature:: With butyllithium; diethylaluminium chloride; methanol; In tetrahydrofuran; hexane; toluene; (N2); hexanic BuLi soln. added to THF soln. of Fe compd. (-78 °C); stirring (30 min); toluenic ClAlEt2 soln. added (-42 °C); stirring (2 h); THF soln. of the camphor added (-78 °C); stirring (2 h); react. mechanism discussed; quenching (excess MeOH); warming (room temp.); evapn. (vac.); column chromd. (SiO2, EtOAc/petroleum); recrystn. (ether/pentane); elem. anal.;