(-)-m-menth-4-yl (1S,2S)-1,2,3,4,6,11-hexahydro-2,5,12-trihydroxy-7-methoxy-2-methyl-6,11-dioxo-1-naphthacenecarboxylate

Base Information

Chemical Name:(-)-m-menth-4-yl (1S,2S)-1,2,3,4,6,11-hexahydro-2,5,12-trihydroxy-7-methoxy-2-methyl-6,11-dioxo-1-naphthacenecarboxylate
CAS No.:103301-83-3
Molecular Formula:C₃₁H₃₆O₈
Molecular Weight:536.622
Hs Code.:

Synonyms:

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Chemical Property of (-)-m-menth-4-yl (1S,2S)-1,2,3,4,6,11-hexahydro-2,5,12-trihydroxy-7-methoxy-2-methyl-6,11-dioxo-1-naphthacenecarboxylate

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Technology Process of (-)-m-menth-4-yl (1S,2S)-1,2,3,4,6,11-hexahydro-2,5,12-trihydroxy-7-methoxy-2-methyl-6,11-dioxo-1-naphthacenecarboxylate

There total 7 articles about (-)-m-menth-4-yl (1S,2S)-1,2,3,4,6,11-hexahydro-2,5,12-trihydroxy-7-methoxy-2-methyl-6,11-dioxo-1-naphthacenecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 103201-62-3
(-)-m-menthyl-4-yl <9,10-dihydro-1,4-dihydroxy-5-methoxy-9,10-dioxo-3-(3-oxobutyl)-2-anthracenyl>acetate

: 103201-63-4
(-)-m-menth-4-yl (1R,2R)-1,2,3,4,6,11-hexahydro-2,5,12-trihydroxy-7-methoxy-2-methyl-6,11-dioxo-1-naphthacenecarboxylate

: 103301-83-3
(-)-m-menth-4-yl (1S,2S)-1,2,3,4,6,11-hexahydro-2,5,12-trihydroxy-7-methoxy-2-methyl-6,11-dioxo-1-naphthacenecarboxylate

Guidance literature:: With N-benzyl-trimethylammonium hydroxide; In pyridine; at -10 ℃; for 0.25h; Yield given. Yields of byproduct given;
DOI:10.1002/jlac.198619860902

Reference yield:

: 103201-42-9
1,4-dihydroxy-8-methoxy-2-<2-(methyl-1,3-dioxolan-2-yl)ethyl>-9,10-anthraquinone

: 103301-83-3
(-)-m-menth-4-yl (1S,2S)-1,2,3,4,6,11-hexahydro-2,5,12-trihydroxy-7-methoxy-2-methyl-6,11-dioxo-1-naphthacenecarboxylate

Guidance literature:: Multi-step reaction with 3 steps

2: 41 percent / p-toluenesulfonic acid / benzene / 12 h / Heating

3: Triton B / pyridine / 0.25 h / -10 °C

With N-benzyl-trimethylammonium hydroxide; toluene-4-sulfonic acid; In pyridine; benzene;
DOI:10.1002/jlac.198619860902

Reference yield:

: 95384-68-2
1,4-dihydroxy-5-methoxy-2-(3-oxobutyl)-9,10-anthraquinone

: 103301-83-3
(-)-m-menth-4-yl (1S,2S)-1,2,3,4,6,11-hexahydro-2,5,12-trihydroxy-7-methoxy-2-methyl-6,11-dioxo-1-naphthacenecarboxylate

Guidance literature:: Multi-step reaction with 4 steps

1: 97 percent / methyl orthoformate, p-toluenesulfonic acid / benzene / 4 h / 55 °C

3: 41 percent / p-toluenesulfonic acid / benzene / 12 h / Heating

4: Triton B / pyridine / 0.25 h / -10 °C

With N-benzyl-trimethylammonium hydroxide; toluene-4-sulfonic acid; trimethyl orthoformate; In pyridine; benzene;
DOI:10.1002/jlac.198619860902