3-(Methoxymethoxy)hex-1-ene

Base Information

• Chemical Name: 3-(Methoxymethoxy)hex-1-ene
• CAS No.: 104620-58-8
• Molecular Formula: C8H16O2
• Molecular Weight: 144.214
• DSSTox Substance ID: DTXSID90546902
• Nikkaji Number: J2.157.948C
• Mol file: 104620-58-8.mol

Synonyms:104620-58-8;3-(Methoxymethoxy)hex-1-ene;SCHEMBL18085186;DTXSID90546902

Chemical Property of 3-(Methoxymethoxy)hex-1-ene

Chemical Property:

• XLogP3: 2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 6
• Exact Mass: 144.115029749
• Heavy Atom Count: 10
• Complexity: 81.3

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC(C=C)OCOC

Technology Process of 3-(Methoxymethoxy)hex-1-ene

There total 1 articles about 3-(Methoxymethoxy)hex-1-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

6-iodo-3-(methoxymethoxy)-1-hexene (851541-78-1) → trans-2-methylcyclopentanol (25144-04-1) + 3-(methoxymethoxy)-1-hexene (104620-58-8) + cis-1-(methoxymethoxy)-2-methylcyclopentane

Guidance literature:

6-iodo-3-(methoxymethoxy)-1-hexene; With tert.-butyl lithium; In diethyl ether; pentane; at -78 ℃; for 0.0833333h;

With N,N,N,N,-tetramethylethylenediamine; In diethyl ether; pentane; at 23 ℃; for 1h; Title compound not separated from byproducts;

DOI:10.1016/j.tet.2005.01.042

Reference yield:

3-(methoxymethoxy)-1-hexene (104620-58-8) → 1-<(1'-hexen-3'-yloxy)methyl>-2-<(hydroxyimino)methyl>-3-methylimidazolium chloride (117983-14-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 74 percent / BCl₃ / pentane; hexane / 1 h / Ambient temperature

2: 39 percent / tetrahydrofuran; dimethylformamide

With boron trichloride; In tetrahydrofuran; hexane; N,N-dimethyl-formamide; pentane;

DOI:10.1021/jm00122a035

upstream raw materials:

6-iodo-3-(methoxymethoxy)-1-hexene

Downstream raw materials:

1-<(1'-hexen-3'-yloxy)methyl>-2-<(hydroxyimino)methyl>-3-methylimidazolium chloride