16,16,16-Trifluororetinal

Base Information

Chemical Name:16,16,16-Trifluororetinal
CAS No.:123522-15-6
Molecular Formula:C₂₀H₂₅F₃O
Molecular Weight:338.413
Hs Code.:

Synonyms:

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Chemical Property of 16,16,16-Trifluororetinal

Chemical Property:

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Technology Process of 16,16,16-Trifluororetinal

There total 15 articles about 16,16,16-Trifluororetinal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 131758-87-7
2,2,2-Trifluoroethyl 1-(trifluoromethyl)-3-methyl-4-oxo-2-cyclohexene-1-carboxylate

: 123522-15-6
16,16,16-Trifluororetinal

Guidance literature:: Multi-step reaction with 12 steps

1: 1) DIBAL-H, 2) MnO₂ / 2) CH₂Cl₂

2: (PhO)3P(CH₃)⁽¹⁺⁾*I^(1-)

3: Li(OtBu)3AlH / diethyl ether

4: 1) KH, 2) n-BuLi / 1) THF, 2) THF, -78 deg C

5: CrO₃*2Py, celite / CH₂Cl₂

6: DBU / diethyl ether / 0 °C

7: n-BuLi

8: DIBAL

9: MnO₂

10: n-BuLi

11: DIBAL

12: MnO₂

With manganese(IV) oxide; n-butyllithium; Celite; methyltriphenoxyphosphonium iodide; potassium hydride; dipyridine chromium trioxide; diisobutylaluminium hydride; 1,8-diazabicyclo[5.4.0]undec-7-ene; lithium tri-t-butoxyaluminum hydride; In diethyl ether; dichloromethane;
DOI:10.1016/S0040-4039(00)95257-2

Reference yield:

: 123522-53-2
1-(Trifluoromethyl)-3-methyl-4-oxo-2-cyclohexene-1-methanol

: 123522-15-6
16,16,16-Trifluororetinal

Guidance literature:: Multi-step reaction with 11 steps

1: (PhO)3P(CH₃)⁽¹⁺⁾*I^(1-)

2: Li(OtBu)3AlH / diethyl ether

3: 1) KH, 2) n-BuLi / 1) THF, 2) THF, -78 deg C

4: CrO₃*2Py, celite / CH₂Cl₂

5: DBU / diethyl ether / 0 °C

6: n-BuLi

7: DIBAL

8: MnO₂

9: n-BuLi

10: DIBAL

11: MnO₂

With manganese(IV) oxide; n-butyllithium; Celite; methyltriphenoxyphosphonium iodide; potassium hydride; dipyridine chromium trioxide; diisobutylaluminium hydride; 1,8-diazabicyclo[5.4.0]undec-7-ene; lithium tri-t-butoxyaluminum hydride; In diethyl ether; dichloromethane;
DOI:10.1016/S0040-4039(00)95257-2

Reference yield:

: 123522-54-3
2-Methyl-4-(iodomethyl)-4-(trifluoromethyl)-2-cyclohexen-1-one

: 123522-15-6
16,16,16-Trifluororetinal

Guidance literature:: Multi-step reaction with 10 steps

1: Li(OtBu)3AlH / diethyl ether

2: 1) KH, 2) n-BuLi / 1) THF, 2) THF, -78 deg C

3: CrO₃*2Py, celite / CH₂Cl₂

4: DBU / diethyl ether / 0 °C

5: n-BuLi

6: DIBAL

7: MnO₂

8: n-BuLi

9: DIBAL

10: MnO₂

With manganese(IV) oxide; n-butyllithium; Celite; potassium hydride; dipyridine chromium trioxide; diisobutylaluminium hydride; 1,8-diazabicyclo[5.4.0]undec-7-ene; lithium tri-t-butoxyaluminum hydride; In diethyl ether; dichloromethane;
DOI:10.1016/S0040-4039(00)95257-2