(+/-)-dicarbonyl[hydridotris(1-pyrazolyl)borate][(η-1,2,3)-1-(p-toluenesulfonyloxy)-2-cyclohexen-1-yl]molybdenum

Base Information

• Chemical Name: (+/-)-dicarbonyl[hydridotris(1-pyrazolyl)borate][(η-1,2,3)-1-(p-toluenesulfonyloxy)-2-cyclohexen-1-yl]molybdenum
• CAS No.: 1237008-34-2
• Molecular Formula: C₂₄H₂₅BMoN₆O₅S
• Molecular Weight: 616.317
• Mol file: 1237008-34-2.mol

Synonyms:

Chemical Property of (+/-)-dicarbonyl[hydridotris(1-pyrazolyl)borate][(η-1,2,3)-1-(p-toluenesulfonyloxy)-2-cyclohexen-1-yl]molybdenum

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (+/-)-dicarbonyl[hydridotris(1-pyrazolyl)borate][(η-1,2,3)-1-(p-toluenesulfonyloxy)-2-cyclohexen-1-yl]molybdenum

There total 1 articles about (+/-)-dicarbonyl[hydridotris(1-pyrazolyl)borate][(η-1,2,3)-1-(p-toluenesulfonyloxy)-2-cyclohexen-1-yl]molybdenum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

[Mo(hydridotris(pyrazolyl)borate)(CO)2(η3-C6H8OTBS)] (1239990-18-1,180892-49-3) + p-toluenesulfonyl chloride (98-59-9) → (+/-)-dicarbonyl[hydridotris(1-pyrazolyl)borate][(η-1,2,3)-1-(p-toluenesulfonyloxy)-2-cyclohexen-1-yl]molybdenum (1237008-34-2)

Guidance literature:

With [(C₄H₉)4N][SiF₂(C₆H₅)3]; In tetrahydrofuran; addn. of tetrabutylammonium salt to THF soln. of molybdenum compd., stirring for 25 min at room temp., addn. of tosyl chloride at 0°C, stirring for 4 h at 0°C; concg., flash chromy. (silica gel, hexanes/ethyl acetate (4:1)), NMR andMS;

DOI:10.1021/om100305f

Reference yield: 45.0%

(+/-)-dicarbonyl[hydridotris(1-pyrazolyl)borate][(η-1,2,3)-1-(p-toluenesulfonyloxy)-2-cyclohexen-1-yl]molybdenum (1237008-34-2) + benzylamine (100-46-9) → (+/-)-dicarbonyl[hydridotris(1-pyrazolyl)borato][(η-1,2,3)-1-benzylamino-2-cyclohexen-1-yl]molybdenum (1237008-55-7)

Guidance literature:

In tetrahydrofuran; addn. of benzylamine to THF soln. of molybdenum compd.., refluxing for 18 h; concg., flash chromy. (silica gel, hexanes/ethyl acetate (4:1)), NMR andMS;

DOI:10.1021/om100305f

upstream raw materials:

[Mo(hydridotris(pyrazolyl)borate)(CO)2(η3-C6H8OTBS)]

p-toluenesulfonyl chloride

Downstream raw materials:

(+/-)-dicarbonyl[hydridotris(1-pyrazolyl)borato][(η-1,2,3)-1-benzylamino-2-cyclohexen-1-yl]molybdenum