RuCo2(CO)9(μ3-C6H5CCC6H5)

Base Information

• Chemical Name: RuCo2(CO)9(μ3-C6H5CCC6H5)
• CAS No.: 87965-60-4
• Molecular Formula: C₂₃H₁₀Co₂O₉Ru
• Molecular Weight: 649.383
• Mol file: 87965-60-4.mol

Synonyms:

Chemical Property of RuCo2(CO)9(μ3-C6H5CCC6H5)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of RuCo2(CO)9(μ3-C6H5CCC6H5)

There total 2 articles about RuCo2(CO)9(μ3-C6H5CCC6H5) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

(C2H5)4N(1+)*RuCo3(CO)10(C2(C6H5)2)(1-)=(C2H5)4N(RuCo3(CO)10C2(C6H5)2) → RuCo2(CO)9(μ3-C6H5CCC6H5) (87965-60-4)

Guidance literature:

With hydrogenchloride; In water; acetone; extn. with hexane;

DOI:10.1016/S0022-328X(00)99849-8

Reference yield:

Co2Ru*11CO = RuCo2(CO)11 + diphenyl acetylene (501-65-5) → RuCo2(CO)9(μ3-C6H5CCC6H5) (87965-60-4)

Guidance literature:

In hexane; PhCCCCPh added to soln. of RuCo2(CO)11 in hexane at -78°C, warmed to room temp., stirred 3h; filtered (silica gel), washed (hexane), evapn. (vac.);

Reference yield: 21.0%

dimethylacetylene (503-17-3) + RuCo2(CO)9(μ3-C6H5CCC6H5) (87965-60-4) + trimethylamine-N-oxide (1184-78-7) → (CO)6Co2(C2Ph2) (14515-69-6) + RuCo2*7CO*C6H5CCC6H5*2CH3CCCH3=RuCo2(CO)7(C6H5CCC6H5)(CH3CCCH3)2

Guidance literature:

In hexane; dichloromethane; byproducts: hexamethylbenzene; excess MeCCMe/hexane added to soln. of RuCo2(CO)9(PhCCPh) in CH2Cl2 at -78°C, slow addn. of soln. of Me3NO in CH2Cl2 (the soln. becomes increasingly deeper red), warmed to room temp. (1h), short heating to 60°C; evapn. (vac.), chromy. (silica gel, hexane/CH2Cl2);

upstream raw materials:

diphenyl acetylene

Downstream raw materials:

RuCoMo(CO)8(C5H5)(μ3-C6H5CCC6H5)

RuCoNi(CO)6(C5H5)(μ3-C6H5CCC6H5)

(CO)6Co₂(C₂Ph₂)