(mesityl)2GeH(fluorenyl)

Base Information

Chemical Name:(mesityl)2GeH(fluorenyl)
CAS No.:108920-31-6
Molecular Formula:C₃₁H₃₂Ge
Molecular Weight:477.185
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (mesityl)2GeH(fluorenyl)

Chemical Property:

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Technology Process of (mesityl)2GeH(fluorenyl)

There total 3 articles about (mesityl)2GeH(fluorenyl) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 108920-25-8
fluorobis(2,4,6-trimethylphenyl)fluorenylgermane

: 108920-31-6
(mesityl)2GeH(fluorenyl)

: 108946-03-8
bis(2,4,6-trimethylphenyl)fluorenylidenegermene

Guidance literature:: With tert.-butyl lithium; In pentane; the organofluorogermane reacted with t-BuLi in pentane at -78 °C;; attempts to isolate it in pure form failed because of the presence of unreacted started material and the formation of organohydrogermane as by-product; (1)H-NMR;;
DOI:10.1021/ja00248a056

Reference yield:

: 16853-85-3
lithium aluminium tetrahydride

: (mesityl)2Ge(fluorenylidene)*Et₂O

: 108920-31-6
(mesityl)2GeH(fluorenyl)

Guidance literature:: Mes2Ge=CR2*Et2O (CR2: fluorenyl) was treated with lithium aluminium hydride;; elemental analysis;;
DOI:10.1021/ja00248a056

Reference yield:

: 108920-25-8
fluorobis(2,4,6-trimethylphenyl)fluorenylgermane

: 132775-05-4
Mes₂FlGeOGeFlMes₂

: 108920-31-6
(mesityl)2GeH(fluorenyl)

: 108946-03-8
bis(2,4,6-trimethylphenyl)fluorenylidenegermene

Guidance literature:: With t-BuLi; In diethyl ether; pentane; byproducts: LiF; (Ar); Schlenk technique; soln. of t-BuLi (1 equiv.) in pentane was slowly added to soln. of Ge compd. in Et2O cooled in dry ice/acetone bath; warmed to room temp.; kept for 1 h at room temp.; evapd. (vac.); triturated with C6D6; centrifuged; not septd.;
DOI:10.1021/om200114n