[Ir2Cl3Cp*2(μ,η3-4-hydroxy-2,1,3-benzothiadiazole-H)]

Base Information

• Chemical Name: [Ir2Cl3Cp*2(μ,η3-4-hydroxy-2,1,3-benzothiadiazole-H)]
• CAS No.: 1389208-55-2
• Molecular Formula: C₂₆H₃₃Cl₃Ir₂N₂OS
• Molecular Weight: 912.426
• Mol file: 1389208-55-2.mol

Synonyms:

Chemical Property of [Ir2Cl3Cp*2(μ,η3-4-hydroxy-2,1,3-benzothiadiazole-H)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ir2Cl3Cp*2(μ,η3-4-hydroxy-2,1,3-benzothiadiazole-H)]

There total 1 articles about [Ir2Cl3Cp*2(μ,η3-4-hydroxy-2,1,3-benzothiadiazole-H)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] (12354-84-6,12354-85-7) + benzo[1,2,5]thiadiazol-4-ol (767-66-8) + toluene (108-88-3,15644-74-3,16713-13-6) → [Ir2Cl3Cp*2(μ,η3-4-hydroxy-2,1,3-benzothiadiazole-H)] (1389208-55-2) + [IrClCp*(4-hydroxy-2,1,3-benzothiadiazole-H)]*0.5toluene

Guidance literature:

With K₂CO₃; In dichloromethane; under Ar using Schlenk techniques; mixt. of Ir complex (0.144 mmol), org. ligand (0.289 mmol) and K2CO3 (0.978 mmol) in CH2Cl2 stirred (24 h, ambient temp.); filtered; washed with CH2Cl2; solvent removed; extd. with toluene; concd.; kept (-25°C); elem. anal.;

DOI:10.1016/j.poly.2012.05.015

upstream raw materials:

bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

benzo[1,2,5]thiadiazol-4-ol

toluene

Refernces