O-(5,10,15,20-tetraphenylporphyrinato)molybdenum(V)OC₆H₁₀OH

Base Information

• Chemical Name: O-(5,10,15,20-tetraphenylporphyrinato)molybdenum(V)OC₆H₁₀OH
• CAS No.: 78261-10-6
• Molecular Formula: C₅₀H₃₉MoN₄O₃
• Molecular Weight: 839.825
• Mol file: 78261-10-6.mol

Synonyms:

Chemical Property of O-(5,10,15,20-tetraphenylporphyrinato)molybdenum(V)OC₆H₁₀OH

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of O-(5,10,15,20-tetraphenylporphyrinato)molybdenum(V)OC₆H₁₀OH

There total 2 articles about O-(5,10,15,20-tetraphenylporphyrinato)molybdenum(V)OC₆H₁₀OH which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Chloro-oxo(5,10,15,20-tetraphenylporphyrinato)molybdenum(V) (69063-76-9,68070-21-3) → (hydroxy)(oxo)(5,10,15,20-tetraphenylporphyrinato)molybdenum(v) (28780-74-7) + O-(5,10,15,20-tetraphenylporphyrinato)molybdenum(V)OOC(CH3)3 (78261-11-7) + O-(5,10,15,20-tetraphenylporphyrinato)molybdenum(V)OC6H10OH (78261-10-6)

Guidance literature:

With tert.-butylhydroperoxide; cyclohexene; In benzene; byproducts: cyclohexene oxide, tert-butyl-2-cyclohexenyl peroxide, OMo(TPP)2O; oxygen free benzene soln. of complex treated with cyclohexene, t-BuOOH at 80°C for 17 h under Ar, further byproduct:cis-O2Mo(TPP);

DOI:10.1021/ja00402a072

Reference yield:

Chloro-oxo(5,10,15,20-tetraphenylporphyrinato)molybdenum(V) (69063-76-9,68070-21-3) + cyclohexane-1,2-epoxide (286-20-4) → O-(5,10,15,20-tetraphenylporphyrinato)molybdenum(V)OC6H10OH (78261-10-6)

Guidance literature:

In benzene; benzene soln. of complex treated with large excess of cyclohexene oxideat room temp.;

DOI:10.1021/ja00402a072

upstream raw materials:

Chloro-oxo(5,10,15,20-tetraphenylporphyrinato)molybdenum(V)

cyclohexane-1,2-epoxide