ZrCl(CH2CMe2Ph)(bis(1,1',2,2'-dimethylsilanodiyl)-η(5)-dicyclopentadienyl)

Base Information

• Chemical Name: ZrCl(CH2CMe2Ph)(bis(1,1',2,2'-dimethylsilanodiyl)-η(5)-dicyclopentadienyl)
• CAS No.: 186383-87-9
• Molecular Formula: C₂₄H₃₁ClSi₂Zr
• Molecular Weight: 502.358
• Mol file: 186383-87-9.mol

Synonyms:

Chemical Property of ZrCl(CH2CMe2Ph)(bis(1,1',2,2'-dimethylsilanodiyl)-η(5)-dicyclopentadienyl)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ZrCl(CH2CMe2Ph)(bis(1,1',2,2'-dimethylsilanodiyl)-η(5)-dicyclopentadienyl)

There total 1 articles about ZrCl(CH2CMe2Ph)(bis(1,1',2,2'-dimethylsilanodiyl)-η(5)-dicyclopentadienyl) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

bis[(μ-dimethylsilyl)(η5-cyclopentadienyl)]dichlorozirconium (154675-56-6) + neophyl lithium (29904-33-4) → ZrCl(CH2CMe2Ph)(bis(1,1',2,2'-dimethylsilanodiyl)-η(5)-dicyclopentadienyl) (186383-87-9)

Guidance literature:

In diethyl ether; Ar-atmosphere; dropwise addn. of 2 equiv. of Li-compd. to Zr-complex soln. at -78°C, stirring (room temp., 12 h); filtration, evapn. (vac.), extn. into hexane, filtration, evapn. of filtrate, recrystn. (hexane, -30°C); elem. anal.;

DOI:10.1016/S0022-328X(96)06569-2

upstream raw materials:

bis[(μ-dimethylsilyl)(η5-cyclopentadienyl)]dichlorozirconium

neophyl lithium