Technology Process of 3-(6-(tricyclohexylstannyl)hexyl)perylene
There total 3 articles about 3-(6-(tricyclohexylstannyl)hexyl)perylene which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
n-butyl lithium;
In
tetrahydrofuran; hexane;
byproducts: C4H9Br; under N2; n-BuLi in hexanes added dropwise to soln. of 3-bromoperylene in THF at -78°C; 10 min; soln. of Sn compd. (1.3 equiv.) in THF added; stirred at -78°C for 1 h; warmed to room temp.; stirred for 20 h; solvent removed; extd. into toluene; org. phase washed; dried (MgSO4); filtered; concd. under reduced pressure; purified by successive column chromy. (silica gel, n-pentane-CH2Cl2); recrystd. from toluene; elem. anal.;
DOI:10.1021/om030478m
- Guidance literature:
-
Multi-step reaction with 3 steps
1: pyridine
2: acetone
3: n-butyl lithium / tetrahydrofuran; hexane
With
n-butyl lithium;
In
tetrahydrofuran; pyridine; hexane; acetone;
DOI:10.1021/om030478m
- Guidance literature:
-
Multi-step reaction with 2 steps
1: acetone
2: n-butyl lithium / tetrahydrofuran; hexane
With
n-butyl lithium;
In
tetrahydrofuran; hexane; acetone;
DOI:10.1021/om030478m
