octahydronaphthalen-4a(2H)-ol

Base Information

• Chemical Name: octahydronaphthalen-4a(2H)-ol
• CAS No.: 1654-87-1
• Molecular Formula: C10H18 O
• Molecular Weight: 154.252
• Mol file: 1654-87-1.mol

Synonyms:4a(2H)-Naphthol,octahydro-, trans- (8CI); trans-9-Decalol; trans-Bicyclo[4.4.0]decan-1-ol;trans-Decalin-9-ol; trans-Octahydro-4a(2H)-naphthol

Chemical Property of octahydronaphthalen-4a(2H)-ol

Chemical Property:

• Vapor Pressure: 0.00698mmHg at 25°C
• Boiling Point: 239.6°C at 760 mmHg
• Flash Point: 98.2°C
• Density: 1.027g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of octahydronaphthalen-4a(2H)-ol

There total 20 articles about octahydronaphthalen-4a(2H)-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

6-bromocyclododecanone (87307-15-1) → cyclodecanone (1502-06-3) + trans-decal-9-ol (1654-87-1) + cis-9-decalol (3574-58-1)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In benzene; at 60 ℃; for 15h;

DOI:10.1021/jo00172a051

Reference yield: 27.0%

trans-Decalin (493-02-7) → trans-decal-9-ol (1654-87-1) + trans-decalin-2-one (4832-17-1,5779-29-3,5779-30-6,16021-08-2,52079-67-1,91684-29-6,91684-30-9,1579-21-1,143392-76-1)

Guidance literature:

With dipotassium hydrogenphosphate; C₁₇H₁₈ClFeN₆O₆^(2-); 3-chloro-benzenecarboperoxoic acid; In water; acetonitrile; at 20 ℃;

DOI:10.1021/acs.orglett.6b03359

Reference yield: 18.0%

trans-Decalin (493-02-7) → trans-decal-9-ol (1654-87-1) + trans-1-decalone (21370-71-8) + trans-decalin-2-one (4832-17-1,5779-29-3,5779-30-6,16021-08-2,52079-67-1,91684-29-6,91684-30-9,1579-21-1,143392-76-1)

Guidance literature:

With methyltrifluoromethyldioxirane; In dichloromethane; at -22 ℃; for 0.183333h;

DOI:10.1021/ja00199a039

upstream raw materials:

Isopropylbenzene

trans-octahydro-[4a]naphthyl hydroperoxide

pyridine N-oxide

cis-decalin

Downstream raw materials:

trans-octahydro-[4a]naphthyl hydroperoxide

2-(4-bromo-butyl)-cyclohexanone

6-bromocyclododecanone

(+/-)-2-(4'-iodobutyl)cyclohexanone