{o-(Ph₂P)C₆H₄}₃Sn(H)

Base Information

Chemical Name:{o-(Ph₂P)C₆H₄}₃Sn(H)
CAS No.:1365617-02-2
Molecular Formula:C₅₄H₄₃P₃Sn
Molecular Weight:903.567
Hs Code.:

{o-(Ph<sub>2</sub>P)C<sub>6</sub>H<sub>4</sub>}<sub>3</sub>Sn(H)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of {o-(Ph₂P)C₆H₄}₃Sn(H)

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Technology Process of {o-(Ph₂P)C₆H₄}₃Sn(H)

There total 1 articles about {o-(Ph₂P)C₆H₄}₃Sn(H) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

: 16853-85-3
lithium aluminium tetrahydride

: 1365617-06-6
{o-(Ph₂P)(C₆H₄)}₃Sn(Cl)

: 1365617-02-2
{o-(Ph₂P)C₆H₄}₃Sn(H)

Guidance literature:: In tetrahydrofuran; under N2; Sn-contg. compd. was dissolved in THF; cooling to -78°C; a suspn. of LiAlH4 in THF was added dropwise to the cold soln.; warming and stirring at room temp. for 12 h; excess LiAlH4 and H2O were addedat -78°C to quench the react.; after warming and stirring at room temp. for 2 h, the soln. was filteredthrough a Celite pad, and the volatiles were removed in vac.; the resid ue was washed with hexane and Et2O and dried under vac.;
DOI:10.1021/om2011276

Reference yield: 85.0%

: 17185-29-4
carbonylhydridetris(triphenylphosphine)rhodium(I)

: 1365617-02-2
{o-(Ph₂P)C₆H₄}₃Sn(H)

: ((Ph₂P)C₆H₄)3SnRh(CO)

Guidance literature:: In toluene; byproducts: PPh3, H2; under N2; a mixt. of Sn-, Rh-contg. compds. (0.269 mmol and 0.269 mmol, resp.) and toluene was stirred at 60-80°C for 12 h; cooling to room temp.; the volatiles were removed under reduced pressure, the residue was washed with Et2O and dried under vac.; elem. anal.;
DOI:10.1021/om2011276

Reference yield:

: carbonylhydridotris(triphenylphosphine)iridium(I)

: 1365617-02-2
{o-(Ph₂P)C₆H₄}₃Sn(H)

: [o-(PPh₂)C₆H₄]3SnIr(CO)

Guidance literature:: In toluene; (under N2, Schlenk); tube filled with Ir-complex, Sn-compound and toluene, stirred at 80°C for 15 h; solvent removed under reduced pressure, washed with Et2O, dried under vac.; elem. anal.;
DOI:10.1039/c2dt30546a