Manganate(1-), tricarbonylbis(dimethylphenylphosphine)-

Base Information

Chemical Name:Manganate(1-), tricarbonylbis(dimethylphenylphosphine)-
CAS No.:104911-22-0
Molecular Formula:C₁₉H₂₂MnO₃P₂
Molecular Weight:415.267
Hs Code.:
Mol file:104911-22-0.mol

Synonyms:

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Chemical Property of Manganate(1-), tricarbonylbis(dimethylphenylphosphine)-

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Technology Process of Manganate(1-), tricarbonylbis(dimethylphenylphosphine)-

There total 3 articles about Manganate(1-), tricarbonylbis(dimethylphenylphosphine)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 49865-17-0,55029-83-9
fac-(OC)3Mn(NCMe)3⁽¹⁺⁾

: 672-66-2
Dimethyl(phenyl)phosphine

: 86708-28-3
(CO)3Mn(P(CH₃)2C₆H₅)2H

: 104911-22-0
(CO)3Mn(P(CH₃)2C₆H₅)2^(1-)

Guidance literature:: In acetonitrile; Electrolysis; electrolysis of cationic Mn-complex as BF4(-) or PF6(-) salt in the presence of 2 eqiv. of PMe2Ph in MeCN containing 0.1 M Et4N(+)ClO4(-) at 25°C under Ar or N2; use of 3 equiv. of PMe2Ph gives 84%, 1 equiv. - 38% yield of the hydride complex; yield of the anionic complex is given according to galvanostatic coulometry data; use of 3 equiv of PMe2Ph gives 84%, 1 equiv - 38% yield of the hydride complex;
DOI:10.1021/om00144a023

Reference yield: 79.0%

: 52745-57-0
fac-(OC)3Mn(NCMe)(PMe₂Ph)2⁽¹⁺⁾

: 86708-28-3
(CO)3Mn(P(CH₃)2C₆H₅)2H

: 104911-22-0
(CO)3Mn(P(CH₃)2C₆H₅)2^(1-)

Guidance literature:: In acetonitrile; Electrolysis; electrolysis of cationic Mn-complex as BF4(-) or PF6(-) salt in MeCN containing 0.1 M Et4N(+)ClO4(-) at 25°C under Ar or N2; yield of anionic complex is given according to galvanostatic coulometry data;
DOI:10.1021/om00144a023

Reference yield: 74.0%

: 52721-00-3,86708-27-2
fac-(OC)3Mn(NCMe)2(PMe₂Ph)⁽¹⁺⁾

: 672-66-2
Dimethyl(phenyl)phosphine

: 86708-28-3
(CO)3Mn(P(CH₃)2C₆H₅)2H

: 104911-22-0
(CO)3Mn(P(CH₃)2C₆H₅)2^(1-)

Guidance literature:: In acetonitrile; Electrolysis; electrolysis of cationic Mn-complex as BF4(-) or PF6(-) salt in the presence of PMe2Ph in MeCN containing 0.1 M Et4N(+)ClO4(-) at 25°C under Ar or N2; yield of the anionic complex is given according to galvanostatic coulometry data;
DOI:10.1021/om00144a023