[4-(2-trifluoromethylphenyl)-2-(2-(2-trifluoromethylphenyl)ethenyl)-6-trimethylsilylpyranyl-η5]tricarbonylmanganese

Base Information

• Chemical Name: [4-(2-trifluoromethylphenyl)-2-(2-(2-trifluoromethylphenyl)ethenyl)-6-trimethylsilylpyranyl-η5]tricarbonylmanganese
• CAS No.: 383401-34-1
• Molecular Formula: C₂₇H₂₁F₆MnO₄Si
• Molecular Weight: 606.475

Synonyms:

Chemical Property of [4-(2-trifluoromethylphenyl)-2-(2-(2-trifluoromethylphenyl)ethenyl)-6-trimethylsilylpyranyl-η5]tricarbonylmanganese

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Technology Process of [4-(2-trifluoromethylphenyl)-2-(2-(2-trifluoromethylphenyl)ethenyl)-6-trimethylsilylpyranyl-η5]tricarbonylmanganese

There total 2 articles about [4-(2-trifluoromethylphenyl)-2-(2-(2-trifluoromethylphenyl)ethenyl)-6-trimethylsilylpyranyl-η5]tricarbonylmanganese which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

[1-(2-trifluoromethylphenyl)-2-[(E)-3-(2-trifluoromethylphenyl)prop-2-en-1-oyl-κO]ethenyl-κC1]tetracarbonylmanganese + trimethylsilylacetylene (1066-54-2) → [4-(2-trifluoromethylphenyl)-2-(2-(2-trifluoromethylphenyl)ethenyl)-6-trimethylsilylpyranyl-η5]tricarbonylmanganese (383401-34-1)

Guidance literature:

In tetrachloromethane; Mn-complex and ligand were dissolved in CCl4, refluxed under N2 for 3 h; CCl4 was removed under vac., CH2Cl2 and alumina were added, rotated, solvent was removed under vac., column with alumina, eluted with CH2Cl2-hexane, crystd. from petroleum spirit; elem. anal.;

DOI:10.1016/S0022-328X(01)01062-2

Reference yield: 20.0%

[1-(2-trifluoromethylphenyl)-2-[(E)-3-(2-trifluoromethylphenyl)prop-2-en-1-oyl-κO]ethenyl-κC1]tetracarbonylmanganese + trimethylsilylacetylene (1066-54-2) → [4-(2-trifluoromethylphenyl)-2-(2-(2-trifluoromethylphenyl)ethenyl)-6-trimethylsilylpyranyl-η5]tricarbonylmanganese (383401-34-1) + [6-oxo-2-trimethylsilyl-4,7-di(2-trifluoromethylphenyl)cyclohepta-1,4-dienyl-1,2,3,4,5-η]tricarbonylmanganese

Guidance literature:

In n-heptane; under N2 atm.; Mn complex and Me3SiCCH under reflux in heptane over 7 ds; sepd. by chromy. on silica layer (1:1 v/v CH2Cl2/petroleum spirit as eluent); crystn. by vapour diffusion (ethyl acetate/petroleum spirit); elem. anal.;

DOI:10.1016/j.jorganchem.2005.04.015

upstream raw materials:

trimethylsilylacetylene

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