(η(5)-C5Me5)(η(3)-N-methoxycarbonyl-5-methoxycarbonyl-6-methyl-2-p-toluenesulfonyl-7-azabicyclo[2.2.1]hepta-2,5-dienyl)RuCl

Base Information

• Chemical Name: (η(5)-C5Me5)(η(3)-N-methoxycarbonyl-5-methoxycarbonyl-6-methyl-2-p-toluenesulfonyl-7-azabicyclo[2.2.1]hepta-2,5-dienyl)RuCl
• CAS No.: 191920-00-0
• Molecular Formula: C₂₈H₃₄ClNO₆RuS
• Molecular Weight: 649.17
• Mol file: 191920-00-0.mol

Synonyms:

Chemical Property of (η(5)-C5Me5)(η(3)-N-methoxycarbonyl-5-methoxycarbonyl-6-methyl-2-p-toluenesulfonyl-7-azabicyclo[2.2.1]hepta-2,5-dienyl)RuCl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η(5)-C5Me5)(η(3)-N-methoxycarbonyl-5-methoxycarbonyl-6-methyl-2-p-toluenesulfonyl-7-azabicyclo[2.2.1]hepta-2,5-dienyl)RuCl

There total 1 articles about (η(5)-C5Me5)(η(3)-N-methoxycarbonyl-5-methoxycarbonyl-6-methyl-2-p-toluenesulfonyl-7-azabicyclo[2.2.1]hepta-2,5-dienyl)RuCl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

chloro(1,5-cyclooctadiene)(pentamethylcyclopentadiene)ruthenium(II) (92390-26-6) + N(COOCH3)C9H9O2SO2C6H4CH3 (160732-49-0) → (η(5)-C5Me5)(η(3)-N-methoxycarbonyl-5-methoxycarbonyl-6-methyl-2-p-toluenesulfonyl-7-azabicyclo[2.2.1]hepta-2,5-dienyl)RuCl (191920-00-0)

Guidance literature:

In tetrahydrofuran; addn. of 1.5 equiv. of ligand to Ru-complex soln., stirring (room temp.,10 h, pptn.); solvent removal (reduced pressure), chromy. (SiO2, EtOAc/petroleum ether=1:1);

DOI:10.1016/S0022-328X(96)06827-1

upstream raw materials:

chloro(1,5-cyclooctadiene)(pentamethylcyclopentadiene)ruthenium(II)

N(COOCH₃)C₉H₉O₂SO₂C₆H₄CH₃