trans-(carbonyl)chlorobis[(phenylethynyl)di-t-butylphosphine]rhodium(I)

Base Information

Chemical Name:trans-(carbonyl)chlorobis[(phenylethynyl)di-t-butylphosphine]rhodium(I)
CAS No.:66152-71-4
Molecular Formula:C₃₃H₄₆ClOP₂Rh
Molecular Weight:659.034
Hs Code.:

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Chemical Property of trans-(carbonyl)chlorobis[(phenylethynyl)di-t-butylphosphine]rhodium(I)

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Technology Process of trans-(carbonyl)chlorobis[(phenylethynyl)di-t-butylphosphine]rhodium(I)

There total 2 articles about trans-(carbonyl)chlorobis[(phenylethynyl)di-t-butylphosphine]rhodium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: di(rhodium)tetracarbonyl dichloride

: 66128-15-2
(phenylethynyl)di-t-butylphosphine

: 66152-71-4
trans-(carbonyl)chlorobis[(phenylethynyl)di-t-butylphosphine]rhodium(I)

Guidance literature:: In methanol; Ar-atmosphere; addn. of 2 equiv. of ligand to Rh-complex soln.; elem. anal.;
DOI:10.1039/DT9770002285

Reference yield:

: 66152-72-5
dichlorohydridobis[(phenylethynyl)di-t-butylphosphine]rhodium(I)

: 66152-71-4
trans-(carbonyl)chlorobis[(phenylethynyl)di-t-butylphosphine]rhodium(I)

Guidance literature:: With carbon monoxide; In not given;
DOI:10.1039/DT9770002285

Reference yield: 95.0%

: 66152-71-4
trans-(carbonyl)chlorobis[(phenylethynyl)di-t-butylphosphine]rhodium(I)

: 683-60-3
sodium isopropylate

: 66118-61-4
carbonyl[2-(di-t-butylphosphino)-1-phenylethyleneoxo-OP][(phenylethynyl)di-t-butylphosphine]rhodium(I)

Guidance literature:: In isopropyl alcohol; refluxing Rh-complex with slight lack of i-PrONa (16 h); evapn., treatment of oil with H2O, filtration; elem. anal.;
DOI:10.1039/DT9770002285