tricarbonyl(η5-pentamethylcyclopentadienyl){(phenylthio)methyl}wolfram

Base Information

Chemical Name:tricarbonyl(η5-pentamethylcyclopentadienyl){(phenylthio)methyl}wolfram
CAS No.:119596-30-4
Molecular Formula:C₂₀H₂₂O₃SW
Molecular Weight:526.309
Hs Code.:

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Chemical Property of tricarbonyl(η5-pentamethylcyclopentadienyl){(phenylthio)methyl}wolfram

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Technology Process of tricarbonyl(η5-pentamethylcyclopentadienyl){(phenylthio)methyl}wolfram

There total 1 articles about tricarbonyl(η5-pentamethylcyclopentadienyl){(phenylthio)methyl}wolfram which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 14040-11-0
tungsten hexacarbonyl

: 7205-91-6
phenylthiomethyl chloride

: 4045-44-7
1,2,3,4,5-pentamethylcyclopentadiene

: 119596-30-4
tricarbonyl(η5-pentamethylcyclopentadienyl){(phenylthio)methyl}wolfram

Guidance literature:: With n-C₄H₉Li; In 1,2-dimethoxyethane; (N2); to soln. of C5HMe5 was added slowly hexane soln. of BuLi at 0°C, to mixt. was added W(CO)6 and refluxed for 60 h, after addn. of chloromethyl phenylsulfide was stirred 30 min at 0°C, then 2 h at 40°C, solvents removed in vac.; residue was dissolved in CH2Cl2 and chromd. (Al2O3; petroleum ether/CH2Cl2), yellow eluate was evapd. in vac., residue recrystd. from petroleum ether/CH2Cl2; elem. anal.;