mer-trichlorotris(dimethylphenylphosphine)tungsten(III)

Base Information

Chemical Name:mer-trichlorotris(dimethylphenylphosphine)tungsten(III)
CAS No.:150653-03-5
Molecular Formula:C₂₄H₃₃Cl₃P₃W
Molecular Weight:704.656
Hs Code.:

Synonyms:

Suppliers and Price of mer-trichlorotris(dimethylphenylphosphine)tungsten(III)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of mer-trichlorotris(dimethylphenylphosphine)tungsten(III)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of mer-trichlorotris(dimethylphenylphosphine)tungsten(III)

There total 7 articles about mer-trichlorotris(dimethylphenylphosphine)tungsten(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 25731-31-1,30411-60-0
WCl₄(PMe₂Ph)₂

: 672-66-2
Dimethyl(phenyl)phosphine

: 135745-75-4,150653-03-5
mer-trichlorotris(dimethylphenylphosphine)tungsten(III)

Guidance literature:: With 2,5-dimethyl-1,4-bis(trimethylsilyl)-1,4-diaza-2,5-cyclohexadiene; In toluene; at 20 ℃; for 14h; Inert atmosphere; Schlenk technique;
DOI:10.1021/ja501313s

Reference yield: 52.0%

: 30411-60-0
WCl₄(PMe₂Ph)2

: 135745-75-4,150653-03-5
mer-trichlorotris(dimethylphenylphosphine)tungsten(III)

Guidance literature:: With Zn; In tetrahydrofuran; soln. of W complex treated with Zn granules at room temp., stirred overnight at room temp.; filtered, evapn., pptn., washed (pentane), extd. into hot ethanol, cooling to room temp.;
DOI:10.1039/DT9920000769

Reference yield: 50.0%

: 47690-18-6
tetrachlorotris(dimethylphenylphosphine)tungsten(IV)

: 135745-75-4,150653-03-5
mer-trichlorotris(dimethylphenylphosphine)tungsten(III)

Guidance literature:: With zinc; In tetrahydrofuran; stirred at room temp. for 2 h under dry dinitrogen, filtered through Celit and concd. to dryness; redissolved in thf, addn. of hexane, 0°C overnight then filtered, washed with Et2O, dried in vac.; recrystn. from thf-hexane, elem. anal.;