nickel(II) dibenzyldithiocarbamate

Base Information

• Chemical Name: nickel(II) dibenzyldithiocarbamate
• CAS No.: 38542-61-9
• Molecular Formula: C₃₀H₂₈N₂NiS₄
• Molecular Weight: 603.52
• Mol file: 38542-61-9.mol

Synonyms:

Chemical Property of nickel(II) dibenzyldithiocarbamate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of nickel(II) dibenzyldithiocarbamate

There total 2 articles about nickel(II) dibenzyldithiocarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sodium dibenzyldithiocarbamate (55310-46-8) + nickel dibromide (13462-88-9) → nickel(II) dibenzyldithiocarbamate (38542-61-9)

Guidance literature:

In acetonitrile; byproducts: NaBr; 2 equiv. Na(dbtc) and 1 equiv. NiBr2 in MeCN was heated at 50°C for 4 h; react. mixt. was cooled, ppt. was dissolved in hot chlorobenzene and filtered, solvent was removed to dryness in vacuo; elem. anal.;

DOI:10.1021/ic051261i

Reference yield:

Ni((C6H5CH2)2NCS2)3(1+)*BF4(1-)*CCl4 = [Ni((C6H5CH2)2NCS2)3]BF4*CCl4 → nickel(II) dibenzyldithiocarbamate (38542-61-9)

Guidance literature:

In acetonitrile; byproducts: Ni(2+), ((C6H5CH2)2NCS2)2; Irradiation (UV/VIS); irradiated (poly- (425-670 nm) and mono- (436 nm) chromatically); photometry; Kinetics;

Reference yield: 58.0%

1,4,8,11-Tetraazacyclotetradecane (295-37-4) + nickel(II) dibenzyldithiocarbamate (38542-61-9) → [Ni(N,N-dibenzyldithiocarbamate)(1,4,8,11-tetraazacyclotetradecane)]ClO4

Guidance literature:

In ethanol; chloroform; 1 equiv. of Ni-compd. in CHCl3 were reacted with 1 equiv. of N-compd. in96% EtOH, reflux for 10 h; soln. was filtered, kept for a few days, recrystn. from CHCl3 with adding of MeOH or hexane, crystals were washed with MeOH or hexane, dried under an IR lamp at 40 °C, elem. anal.;

DOI:10.1016/j.poly.2007.09.024

upstream raw materials:

sodium dibenzyldithiocarbamate

nickel dibromide

Refernces