closo-2,2-bis(triphenylphosphine)-1-selena-2-platinadodecaborane⁽¹⁰⁾*CH₂Cl₂

Base Information

• Chemical Name: closo-2,2-bis(triphenylphosphine)-1-selena-2-platinadodecaborane⁽¹⁰⁾*CH₂Cl₂
• CAS No.: 108792-93-4
• Molecular Formula: CH₂Cl₂*C₃₆H₄₀B₁₀P₂PtSe
• Molecular Weight: 1001.74
• Mol file: 108792-93-4.mol

Synonyms:

Chemical Property of closo-2,2-bis(triphenylphosphine)-1-selena-2-platinadodecaborane⁽¹⁰⁾*CH₂Cl₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of closo-2,2-bis(triphenylphosphine)-1-selena-2-platinadodecaborane⁽¹⁰⁾*CH₂Cl₂

There total 2 articles about closo-2,2-bis(triphenylphosphine)-1-selena-2-platinadodecaborane⁽¹⁰⁾*CH₂Cl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

tetrakis(triphenylphosphine)platinum (14221-02-4) + 1-selena-closo-dodecaborane(11) (68027-10-1) → closo-2,2-bis(triphenylphosphine)-1-selena-2-platinadodecaborane(10)*CH2Cl2 (108792-93-4) + (PtH(P(C6H5)3)3)(1+)*(SeB10H11)(1-)={PtH(P(C6H5)3)3}(SeB10H11)

Guidance literature:

With CH₂Cl₂; In ethanol; Soln. of reagents in ethanol was refluxed for 18 h ( N2 atm.) ;; cooling, brown and orange products were sepd.; recrystd. from EtOH-CH2Cl2 (25°C); elem. anal.;;

DOI:10.1039/DT9870000699

Reference yield:

(PtH(P(C6H5)3)3)(1+)*(SeB10H11)(1-)={PtH(P(C6H5)3)3}(SeB10H11) → 1-selena-closo-dodecaborane(11) (68027-10-1) + closo-2,2-bis(triphenylphosphine)-1-selena-2-platinadodecaborane(10)*CH2Cl2 (108792-93-4)

Guidance literature:

In ethanol; ethanol, reflux, 18 h;; thin-layer chromy.;;

DOI:10.1039/DT9870000699

upstream raw materials:

tetrakis(triphenylphosphine)platinum

1-selena-closo-dodecaborane⁽¹¹⁾