N-[bis(isopropoxy)-thiophosphoryl]-N'-phenylthiourea gold(I) triphenylphosphane

Base Information

• Chemical Name: N-[bis(isopropoxy)-thiophosphoryl]-N'-phenylthiourea gold(I) triphenylphosphane
• CAS No.: 729573-06-2
• Molecular Formula: C₃₁H₃₅AuN₂O₂P₂S₂
• Molecular Weight: 790.677
• Mol file: 729573-06-2.mol

Synonyms:

Chemical Property of N-[bis(isopropoxy)-thiophosphoryl]-N'-phenylthiourea gold(I) triphenylphosphane

Chemical Property:

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Technology Process of N-[bis(isopropoxy)-thiophosphoryl]-N'-phenylthiourea gold(I) triphenylphosphane

There total 2 articles about N-[bis(isopropoxy)-thiophosphoryl]-N'-phenylthiourea gold(I) triphenylphosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

trifluoromethanesulfonyloxy(triphenylphosphine)gold(I) (156397-47-6) + N-[bis(isopropoxy)-thiophosphoryl]-N'-phenylthiourea (69674-01-7) → N-[bis(isopropoxy)-thiophosphoryl]-N'-phenylthiourea gold(I) triphenylphosphane (729573-06-2)

Guidance literature:

With KOH; In methanol; ligand to Au=1:1, KOH and ligand added to Au complex in CH3OH, stirred for 15 min; concd., pptd.(n-hexane), elem. anal.;

DOI:10.1002/ejic.200300328

Reference yield: 48.0%

gold (acetylacetonato) triphenylphosphane + N-[bis(isopropoxy)-thiophosphoryl]-N'-phenylthiourea (69674-01-7) → N-[bis(isopropoxy)-thiophosphoryl]-N'-phenylthiourea gold(I) triphenylphosphane (729573-06-2)

Guidance literature:

In dichloromethane; ligand to Au=1:1, ligand added to Au complex in CH2Cl2, stirred for 15 min; filtered (celite), concd., pptd.(n-hexane), recrystd.(CH2Cl2/hexane), elem. anal.;

DOI:10.1002/ejic.200300328

upstream raw materials:

N-[bis(isopropoxy)-thiophosphoryl]-N'-phenylthiourea

trifluoromethanesulfonyloxy(triphenylphosphine)gold(I)