Benzoic acid (1R,3R)-3-acetoxy-2-[(E)-(R)-4-acetoxy-6-methoxycarbonyl-hex-2-en-(Z)-ylidene]-3-((Z)-oct-2-enyl)-cyclopentyl ester

Base Information

• Chemical Name: Benzoic acid (1R,3R)-3-acetoxy-2-[(E)-(R)-4-acetoxy-6-methoxycarbonyl-hex-2-en-(Z)-ylidene]-3-((Z)-oct-2-enyl)-cyclopentyl ester
• CAS No.: 87654-90-8
• Molecular Formula: C₃₂H₄₂O₈
• Molecular Weight: 554.681
• Mol file: 87654-90-8.mol

Synonyms:

Chemical Property of Benzoic acid (1R,3R)-3-acetoxy-2-[(E)-(R)-4-acetoxy-6-methoxycarbonyl-hex-2-en-(Z)-ylidene]-3-((Z)-oct-2-enyl)-cyclopentyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzoic acid (1R,3R)-3-acetoxy-2-[(E)-(R)-4-acetoxy-6-methoxycarbonyl-hex-2-en-(Z)-ylidene]-3-((Z)-oct-2-enyl)-cyclopentyl ester

There total 4 articles about Benzoic acid (1R,3R)-3-acetoxy-2-[(E)-(R)-4-acetoxy-6-methoxycarbonyl-hex-2-en-(Z)-ylidene]-3-((Z)-oct-2-enyl)-cyclopentyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

claviridenone-d (85700-42-1) → Benzoic acid (1R,3R)-3-acetoxy-2-[(E)-(R)-4-acetoxy-6-methoxycarbonyl-hex-2-en-(Z)-ylidene]-3-((Z)-oct-2-enyl)-cyclopentyl ester (87654-90-8)

Guidance literature:

Multi-step reaction with 3 steps

1: benzene / 40 h / 20 °C / Irradiation

2: 850 mg / NaBH₄ / tetrahydrofuran; methanol / 0.17 h / 0 °C

3: 19 mg / pyridine / 0.17 h / 22 °C

With pyridine; sodium tetrahydroborate; In tetrahydrofuran; methanol; benzene;

DOI:10.1016/S0040-4020(01)96467-1

Reference yield:

5E,7E-Clavulone II (85700-43-2) → Benzoic acid (1R,3R)-3-acetoxy-2-[(E)-(R)-4-acetoxy-6-methoxycarbonyl-hex-2-en-(Z)-ylidene]-3-((Z)-oct-2-enyl)-cyclopentyl ester (87654-90-8)

Guidance literature:

Multi-step reaction with 2 steps

1: 850 mg / NaBH₄ / tetrahydrofuran; methanol / 0.17 h / 0 °C

2: 19 mg / pyridine / 0.17 h / 22 °C

With pyridine; sodium tetrahydroborate; In tetrahydrofuran; methanol;

DOI:10.1016/S0040-4020(01)96467-1

Reference yield:

claviridenone-a (85611-86-5) → Benzoic acid (1R,3R)-3-acetoxy-2-[(E)-(R)-4-acetoxy-6-methoxycarbonyl-hex-2-en-(Z)-ylidene]-3-((Z)-oct-2-enyl)-cyclopentyl ester (87654-90-8)

Guidance literature:

Multi-step reaction with 3 steps

1: benzene / 40 h / 20 °C / Irradiation

2: 850 mg / NaBH₄ / tetrahydrofuran; methanol / 0.17 h / 0 °C

3: 19 mg / pyridine / 0.17 h / 22 °C

With pyridine; sodium tetrahydroborate; In tetrahydrofuran; methanol; benzene;

DOI:10.1016/S0040-4020(01)96467-1

upstream raw materials:

benzoyl chloride

(E)-(R)-4-Acetoxy-7-[(2R,5R)-2-acetoxy-5-hydroxy-2-((Z)-oct-2-enyl)-cyclopent-(Z)-ylidene]-hept-5-enoic acid methyl ester

claviridenone-d

5E,7E-Clavulone II