(S)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (S)-1-[(R)-1-((S)-3,3,3-trifluoro-2-methoxy-2-phenyl-propionyloxy)-propyl]-hex-5-enyl ester

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Chemical Name:(S)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (S)-1-[(R)-1-((S)-3,3,3-trifluoro-2-methoxy-2-phenyl-propionyloxy)-propyl]-hex-5-enyl ester
CAS No.:104640-16-6
Molecular Formula:C₂₉H₃₂F₆O₆
Molecular Weight:590.56
Hs Code.:

(S)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (S)-1-[(R)-1-((S)-3,3,3-trifluoro-2-methoxy-2-phenyl-propionyloxy)-propyl]-hex-5-enyl ester

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Chemical Property of (S)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (S)-1-[(R)-1-((S)-3,3,3-trifluoro-2-methoxy-2-phenyl-propionyloxy)-propyl]-hex-5-enyl ester

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Technology Process of (S)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (S)-1-[(R)-1-((S)-3,3,3-trifluoro-2-methoxy-2-phenyl-propionyloxy)-propyl]-hex-5-enyl ester

There total 8 articles about (S)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (S)-1-[(R)-1-((S)-3,3,3-trifluoro-2-methoxy-2-phenyl-propionyloxy)-propyl]-hex-5-enyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 616-25-1
1-Penten-3-ol

: 100699-17-0,100762-82-1,104640-15-5,104640-16-6
(S)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (R)-1-[(S)-1-((S)-3,3,3-trifluoro-2-methoxy-2-phenyl-propionyloxy)-propyl]-hex-5-enyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 1) Ti(i-PrO)4, diisopropyl D-(-)-tartrate, t-BuOOH, 2) PPTS / 1) CH₂Cl₂, -20 deg C, 15 h, 2) CH₂Cl₂, r.t., 20 h

2: 1) Cu₂Br₂ / 1) THF, -30 deg C, 10 min, 2) THF, -30 to 5 deg C, several hours

3: 54 percent / N HCl / tetrahydrofuran / 2.5 h

4: 4-(N,N-dimethylamino)pyridine, Et₃N / CH₂Cl₂ / Ambient temperature; several hours

With copper(I) bromide; titanium(IV) isopropylate; hydrogenchloride; tert.-butylhydroperoxide; dmap; pyridinium p-toluenesulfonate; D-(-)-diisopropyl tartrate; triethylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1016/S0040-4020(01)96695-5

Reference yield:

: 616-25-1
1-Penten-3-ol

: 100699-17-0,100762-82-1,104640-15-5,104640-16-6
(S)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (S)-1-[(R)-1-((S)-3,3,3-trifluoro-2-methoxy-2-phenyl-propionyloxy)-propyl]-hex-5-enyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 1) Ti(i-PrO)4, diisopropyl D-(-)-tartrate, t-BuOOH, 2) PPTS / 1) CH₂Cl₂, -20 deg C, 15 h, 2) CH₂Cl₂, r.t., 20 h

2: 1) Cu₂Br₂ / 1) THF, -30 deg C, 10 min, 2) THF, -30 to 5 deg C, several hours

3: 33.6 percent / N HCl / tetrahydrofuran / 2.5 h

4: 4-(N,N-dimethylamino)pyridine, Et₃N / CH₂Cl₂ / Ambient temperature; several hours

With copper(I) bromide; titanium(IV) isopropylate; hydrogenchloride; tert.-butylhydroperoxide; dmap; pyridinium p-toluenesulfonate; D-(-)-diisopropyl tartrate; triethylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1016/S0040-4020(01)96695-5

Reference yield:

: 100699-15-8,135503-06-9
(2R,3S)-1,2-Epoxy-3-pentanol 1-Ethoxyethyl Ether

: 100699-17-0,100762-82-1,104640-15-5,104640-16-6
(S)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (R)-1-[(S)-1-((S)-3,3,3-trifluoro-2-methoxy-2-phenyl-propionyloxy)-propyl]-hex-5-enyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 1) Cu₂Br₂ / 1) THF, -30 deg C, 10 min, 2) THF, -30 to 5 deg C, several hours

2: 54 percent / N HCl / tetrahydrofuran / 2.5 h

3: 4-(N,N-dimethylamino)pyridine, Et₃N / CH₂Cl₂ / Ambient temperature; several hours

With copper(I) bromide; hydrogenchloride; dmap; triethylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1016/S0040-4020(01)96695-5