[2-tert-butyl-6-((2,6-bis(3,5-bis(trifluoromethyl)phenyl)phenylimino)methyl)phenolato]nickel(II) chloro 2,4-lutidine

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Chemical Name:[2-tert-butyl-6-((2,6-bis(3,5-bis(trifluoromethyl)phenyl)phenylimino)methyl)phenolato]nickel(II) chloro 2,4-lutidine
CAS No.:1374460-53-3
Molecular Formula:C₄₀H₃₁ClF₁₂N₂NiO
Molecular Weight:877.823
Hs Code.:

Synonyms:

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Chemical Property of [2-tert-butyl-6-((2,6-bis(3,5-bis(trifluoromethyl)phenyl)phenylimino)methyl)phenolato]nickel(II) chloro 2,4-lutidine

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Technology Process of [2-tert-butyl-6-((2,6-bis(3,5-bis(trifluoromethyl)phenyl)phenylimino)methyl)phenolato]nickel(II) chloro 2,4-lutidine

There total 1 articles about [2-tert-butyl-6-((2,6-bis(3,5-bis(trifluoromethyl)phenyl)phenylimino)methyl)phenolato]nickel(II) chloro 2,4-lutidine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

: 24884-44-4
{NiCl2(α.γ-(CH3)2C5H3N)2}

: 1374460-49-7
sodium 2-tert-butyl-6-((2,6-bis(3,5-bis(trifluoromethyl)phenyl)phenylimino)methyl)phenolate

: 1374460-53-3
[2-tert-butyl-6-((2,6-bis(3,5-bis(trifluoromethyl)phenyl)phenylimino)methyl)phenolato]nickel(II) chloro 2,4-lutidine

Guidance literature:: In tetrahydrofuran; under N2; THF added to ligand salt; transferred slowly over 20 min to Nicomplex in THF; stirred at room temp. for 90 min; volatiles removed in vac.; CH2Cl2 added; filtered; filtrate concd. in vac.; pentane added; cooled to -40°C overnight; filtered at -78°C; solid dried under high vac.;
DOI:10.1021/om3002735

Reference yield: 67.0%

: 1374460-53-3
[2-tert-butyl-6-((2,6-bis(3,5-bis(trifluoromethyl)phenyl)phenylimino)methyl)phenolato]nickel(II) chloro 2,4-lutidine

: 2386-64-3
ethylmagnesium chloride

: 1374460-54-4
[2-tert-butyl-6-((2,6-bis(3,5-bis(trifluoromethyl)phenyl)phenylimino)methyl)phenolato]nickel(II) ethyl 2,4-lutidine

Guidance literature:: In diethyl ether; under N2; Ni complex in ether cooled to -78°C; EtMgCl added dropwise; stirred at -78°C for 2 h and at -42°C for 1 h; warmedto room temp.; filtered; volatiles removed from filtrate under high vac.; triturated with n-pentane; elem. anal.;
DOI:10.1021/om3002735