AgCl(triphenylphosphine)₂(2-mercaptothiazolidine)

Base Information

• Chemical Name: AgCl(triphenylphosphine)₂(2-mercaptothiazolidine)
• CAS No.: 129485-22-9
• Molecular Formula: C₃₉H₃₅AgClNP₂S₂
• Molecular Weight: 787.114
• Mol file: 129485-22-9.mol

Synonyms:

Chemical Property of AgCl(triphenylphosphine)₂(2-mercaptothiazolidine)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of AgCl(triphenylphosphine)₂(2-mercaptothiazolidine)

There total 3 articles about AgCl(triphenylphosphine)₂(2-mercaptothiazolidine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

thiazolidine-2-thione (134469-06-0) + [AgCl(PPh3)]4 → [silver(I)chloride(η1-thiazolidine-2-thione)(PPh3)2] (129485-22-9)

Guidance literature:

In acetone; addn. the starting Ag-complex and the thione to acetone, refluxing for 30 min, stirring for 2 h at 40°C; filtn., slow evapn. at room temp., filtn. the obtained crystals, washing (ethanol and ether), drying in vacuum, elem. anal.;

DOI:10.1016/S0020-1693(00)80863-4

Reference yield: 71.0%

thiazolidine-2-thione (134469-06-0) + triphenylphosphine (603-35-0) + silver(I) chloride → [silver(I)chloride(η1-thiazolidine-2-thione)(PPh3)2] (129485-22-9)

Guidance literature:

In chloroform; acetonitrile; PPh3 (0.34 mmol) added to suspn. of AgCl (0.17 mmol) (MeCN), stirred for24 h, ppt. filtered, dried (vac.), suspended in chloroform, NSC3H5(S) ( 0.17 mmol) added, stirred; soln. evapd. at room temp., solid dissolved in CH2Cl2, layered with MeOH, crystd.; elem. anal.;

DOI:10.1016/j.ica.2010.06.051

Reference yield: 62.0%

thiazolidine-2-thione (134469-06-0) + triphenylphosphine (603-35-0) + silver(I) chloride → AgCl(triphenylphosphine)2(2-mercaptothiazolidine) (129485-22-9)

Guidance literature:

In toluene; for 2h; Reflux;

DOI:10.1007/s00775-014-1089-6

upstream raw materials:

thiazolidine-2-thione

triphenylphosphine