(3S,4R,5R,7S)-1-benzyl-3-O-benzyl-7-benzyloxymethyl-4,5-O-cyclohexylidene-3,4,5-trihydroxyazepane

Base Information

• Chemical Name: (3S,4R,5R,7S)-1-benzyl-3-O-benzyl-7-benzyloxymethyl-4,5-O-cyclohexylidene-3,4,5-trihydroxyazepane
• CAS No.: 943032-44-8
• Molecular Formula: C₃₄H₄₁NO₄
• Molecular Weight: 527.704
• Mol file: 943032-44-8.mol

Synonyms:

Chemical Property of (3S,4R,5R,7S)-1-benzyl-3-O-benzyl-7-benzyloxymethyl-4,5-O-cyclohexylidene-3,4,5-trihydroxyazepane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (3S,4R,5R,7S)-1-benzyl-3-O-benzyl-7-benzyloxymethyl-4,5-O-cyclohexylidene-3,4,5-trihydroxyazepane

There total 1 articles about (3S,4R,5R,7S)-1-benzyl-3-O-benzyl-7-benzyloxymethyl-4,5-O-cyclohexylidene-3,4,5-trihydroxyazepane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(1R,2R,3S)-3-O-Benzyl-5-benzyloxymethyl-1,2-O-cyclohexylidene-cyclohex-4-en-1,2,3-triol (135735-90-9) → (3S,4R,5R,7S)-1-benzyl-3-O-benzyl-7-benzyloxymethyl-4,5-O-cyclohexylidene-3,4,5-trihydroxyazepane (943032-44-8)

Guidance literature:

Multi-step reaction with 2 steps

1.1: O₃; PPh₃

1.2: aq. NaHCO₃ / ethyl acetate

2.1: NaBH(OAc)3 / CH₂Cl₂ / 20 °C

With sodium tris(acetoxy)borohydride; ozone; triphenylphosphine; In dichloromethane;

DOI:10.1021/jo070058x

upstream raw materials:

(1R,2R,3S)-3-O-Benzyl-5-benzyloxymethyl-1,2-O-cyclohexylidene-cyclohex-4-en-1,2,3-triol