(Z)-(η5-cyclopentadienyl){2-phenyl-4-(phenylmethylene)-1-oxa-3-azonia-2-butene-1,4-diyl}(triisopropylphosphane)rhodium-PF6

Base Information

• Chemical Name: (Z)-(η5-cyclopentadienyl){2-phenyl-4-(phenylmethylene)-1-oxa-3-azonia-2-butene-1,4-diyl}(triisopropylphosphane)rhodium-PF6
• CAS No.: 104067-73-4
• Molecular Formula: C₂₉H₃₈NOPRh*F₆P
• Molecular Weight: 695.47
• Mol file: 104067-73-4.mol

Synonyms:

Chemical Property of (Z)-(η5-cyclopentadienyl){2-phenyl-4-(phenylmethylene)-1-oxa-3-azonia-2-butene-1,4-diyl}(triisopropylphosphane)rhodium-PF6

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (Z)-(η5-cyclopentadienyl){2-phenyl-4-(phenylmethylene)-1-oxa-3-azonia-2-butene-1,4-diyl}(triisopropylphosphane)rhodium-PF6

There total 1 articles about (Z)-(η5-cyclopentadienyl){2-phenyl-4-(phenylmethylene)-1-oxa-3-azonia-2-butene-1,4-diyl}(triisopropylphosphane)rhodium-PF6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

ammonium hexafluorophosphate + (Z)-(η5-cyclopentadienyl){2-phenyl-4-(phenylmethylene)-1-oxa-3-aza-2-butene-1,4-diyl}(triisopropylphosphane)rhodium (104067-69-8) + trifluoroacetic acid (76-05-1) → (Z)-(η5-cyclopentadienyl){2-phenyl-4-(phenylmethylene)-1-oxa-3-azonia-2-butene-1,4-diyl}(triisopropylphosphane)rhodium-PF6 (104067-73-4)

Guidance literature:

In methanol; diethyl ether; under Ar, soln. of Rh-compound and excess CF3CO2H in ether stirred for 5 min, evapn. of solvent in vac., dissolved in methanol, addn. of NH4PF6 and stirred for 10 min; removal of solvent in vac., extn. (CH2Cl2), soln. evapd. to dryness, washed with ether and pentane, dried; elem. anal.;

Reference yield:

(Z)-(η5-cyclopentadienyl){2-phenyl-4-(phenylmethylene)-1-oxa-3-azonia-2-butene-1,4-diyl}(triisopropylphosphane)rhodium-PF6 (104067-73-4) → (E)-(η5-cyclopentadienyl){2-phenyl-4-(phenylmethylene)-1-oxa-3-azonia-2-butene-1,4-diyl}(triisopropylphosphane)rhodium-PF6 (104112-54-1)

Guidance literature:

In nitromethane-d3; under Ar, in a closed NMR tube, 28 d at room temp.; 1:1-mixture, detected by (1)H-NMR;

upstream raw materials:

(Z)-(η5-cyclopentadienyl){2-phenyl-4-(phenylmethylene)-1-oxa-3-aza-2-butene-1,4-diyl}(triisopropylphosphane)rhodium

trifluoroacetic acid

Downstream raw materials:

(E)-(η5-cyclopentadienyl){2-phenyl-4-(phenylmethylene)-1-oxa-3-azonia-2-butene-1,4-diyl}(triisopropylphosphane)rhodium-PF6