(racemic)-(1,1'-binaphthyl-2,2'-dioxy)PN(CHMe₂)PPh₂

Base Information

Chemical Name:(racemic)-(1,1'-binaphthyl-2,2'-dioxy)PN(CHMe₂)PPh₂
CAS No.:171878-46-9
Molecular Formula:C₃₅H₂₉NO₂P₂
Molecular Weight:557.568
Hs Code.:

(racemic)-(1,1'-binaphthyl-2,2'-dioxy)PN(CHMe<sub>2</sub>)PPh<sub>2</sub>

Synonyms:

Suppliers and Price of (racemic)-(1,1'-binaphthyl-2,2'-dioxy)PN(CHMe₂)PPh₂

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (racemic)-(1,1'-binaphthyl-2,2'-dioxy)PN(CHMe₂)PPh₂

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (racemic)-(1,1'-binaphthyl-2,2'-dioxy)PN(CHMe₂)PPh₂

There total 2 articles about (racemic)-(1,1'-binaphthyl-2,2'-dioxy)PN(CHMe₂)PPh₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 602-09-5
1,1'-bi-2-naphthol

: 171878-46-9,848492-07-9,848492-78-4
(racemic)-(1,1'-binaphthyl-2,2'-dioxy)PN(CHMe₂)PPh₂

Guidance literature:: Multi-step reaction with 2 steps

1: PCl₃; Et₃N / toluene / -78 °C

2: Et₃N / toluene / 12 h

With triethylamine; phosphorus trichloride; In toluene;
DOI:10.1016/j.jorganchem.2004.09.082

Reference yield:

: 31036-96-1
diphenylphosphino isopropylamine

: 137156-22-0,171878-71-0,155613-52-8
binaphthol chlorophosphite

: 171878-46-9,848492-07-9,848492-78-4
(racemic)-(1,1'-binaphthyl-2,2'-dioxy)PN(CHMe₂)PPh₂

Guidance literature:: With triethylamine; In toluene; Yield given; Ambient temperature;

Reference yield: 90.0%

: ammonium hexafluorophosphate

: di-μ-chlorobis[(η(3)-1,3-dimethylallyl)palladium(II)]

: 171878-46-9,848492-07-9,848492-78-4
(racemic)-(1,1'-binaphthyl-2,2'-dioxy)PN(CHMe₂)PPh₂

: 848492-13-7,848418-10-0
[Pd(η3-1,3-Me2-allyl)(κ2-(racemic)-(1,1'-binaphthyl-2,2'-dioxy)PN(CHMe2)PPh2)](PF6)

Guidance literature:: In acetone; under N2; mixt. of Pd complex, NH4PF6 and ligand dissolved in acetone; stirred at 25°C for 1 h; filtered; filtrate concd. under reduced pressure; crystd. by hexane layering; elem. anal.; mixt. of two diastereomers obtained;
DOI:10.1016/j.jorganchem.2004.09.082