[Re(nitrosyl)2(triisopropylphosphine)2(C(Me)SePh)][tetrakis(3,5-bis(trifluoromethyl)phenyl)borate]

Base Information

• Chemical Name: [Re(nitrosyl)2(triisopropylphosphine)2(C(Me)SePh)][tetrakis(3,5-bis(trifluoromethyl)phenyl)borate]
• CAS No.: 1189393-28-9
• Molecular Formula: C₂₆H₅₀N₂O₂P₂ReSe*C₃₂H₁₂BF₂₄
• Molecular Weight: 1613.03
• Mol file: 1189393-28-9.mol

Synonyms:

Chemical Property of [Re(nitrosyl)2(triisopropylphosphine)2(C(Me)SePh)][tetrakis(3,5-bis(trifluoromethyl)phenyl)borate]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Re(nitrosyl)2(triisopropylphosphine)2(C(Me)SePh)][tetrakis(3,5-bis(trifluoromethyl)phenyl)borate]

There total 1 articles about [Re(nitrosyl)2(triisopropylphosphine)2(C(Me)SePh)][tetrakis(3,5-bis(trifluoromethyl)phenyl)borate] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

[Re(nitrosyl)2(triisopropylphosphine)2(CCH2)][tetrakis(3,5-bis(trifluoromethyl)phenyl)borate] (1189393-14-3) + Benzeneselenol (645-96-5) → [Re(nitrosyl)2(triisopropylphosphine)2(C(Me)SePh)][tetrakis(3,5-bis(trifluoromethyl)phenyl)borate] (1189393-28-9)

Guidance literature:

In dichloromethane; (N2); using Schlenk techniques; addn. of slight excess of benzeneselenolto CH2Cl2 soln. of Re(NO)2(P(i-Pr)3)2(CCH2)(B(C6H3(CF3)2)4) at room tem p.; stirring for 10 min; removal of volatiles under reduced pressure, washing with pentane; drying under reduced pressure; elem. anal.;

DOI:10.1021/om9003412

upstream raw materials:

[Re(nitrosyl)2(triisopropylphosphine)2(CCH₂)][tetrakis(3,5-bis(trifluoromethyl)phenyl)borate]

Benzeneselenol