(2E,4E,6E)-7-Trimethylsilanyl-hepta-2,4,6-trienethioic acid S-phenyl ester

Base Information

• Chemical Name: (2E,4E,6E)-7-Trimethylsilanyl-hepta-2,4,6-trienethioic acid S-phenyl ester
• CAS No.: 145653-30-1
• Molecular Formula: C₁₆H₂₀OSSi
• Molecular Weight: 288.486
• Mol file: 145653-30-1.mol

Synonyms:

Chemical Property of (2E,4E,6E)-7-Trimethylsilanyl-hepta-2,4,6-trienethioic acid S-phenyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2E,4E,6E)-7-Trimethylsilanyl-hepta-2,4,6-trienethioic acid S-phenyl ester

There total 1 articles about (2E,4E,6E)-7-Trimethylsilanyl-hepta-2,4,6-trienethioic acid S-phenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

phenyl chlorothioformate (13464-19-2) + (1E,3E,5E)-1,6-bis(trimethylsilyl)hexa-1,3,5-triene (133683-82-6) → (2E,4E,6E)-7-Trimethylsilanyl-hepta-2,4,6-trienethioic acid S-phenyl ester (145653-30-1)

Guidance literature:

With aluminium trichloride; Yield given. Multistep reaction; 1.) CH₂Cl₂, 0 deg C, 10 min, 2.) 0 deg C;

DOI:10.1016/S0040-4039(00)60935-8

Reference yield:

(2E,4E,6E)-7-Trimethylsilanyl-hepta-2,4,6-trienethioic acid S-phenyl ester (145653-30-1) → Trimethyl-((1E,3E,5Z)-6-phenylsulfanyl-hexa-1,3,5-trienyl)-silane (145653-28-7) + Trimethyl-((1E,3E,5E)-6-phenylsulfanyl-hexa-1,3,5-trienyl)-silane (145653-31-2)

Guidance literature:

With RhCl(PPh₃)3; In N,N-dimethyl-formamide; at 80 ℃; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1016/S0040-4039(00)60935-8

upstream raw materials:

phenyl chlorothioformate

(1E,3E,5E)-1,6-bis(trimethylsilyl)hexa-1,3,5-triene

Downstream raw materials:

Trimethyl-((1E,3E,5Z)-6-phenylsulfanyl-hexa-1,3,5-trienyl)-silane

Trimethyl-((1E,3E,5E)-6-phenylsulfanyl-hexa-1,3,5-trienyl)-silane