(+/-)-MYRICANOL

Base Information

Chemical Name:(+/-)-MYRICANOL
CAS No.:181228-75-1
Molecular Formula:C₂₁H₂₆O₅
Molecular Weight:358.434
Hs Code.:
Mol file:181228-75-1.mol

Synonyms:

Suppliers and Price of (+/-)-MYRICANOL

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 12 raw suppliers

Chemical Property of (+/-)-MYRICANOL

Chemical Property:

Melting Point:205-206°C

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (+/-)-MYRICANOL

There total 11 articles about (+/-)-MYRICANOL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 90052-02-1,449729-89-9
(+)-S-myricanol 5-O-β-D-glucopyranoside

: 181228-75-1,32630-90-3
Myricanol

Guidance literature:: With acetate buffer; β-glucosidase; at 38 ℃; for 48h; pH=4.4;
DOI:10.1248/cpb.50.208

Reference yield:

: 1335227-07-0
2-(benzyloxy)-1-bromo-3,4-dimethoxybenzene

: 33606-81-4,32630-90-3
(-)-aR-11R-myricanol

: 181228-75-1,32630-90-3
Myricanol

Guidance literature:: Multi-step reaction with 8 steps

1: di‐tert‐butyl‐(1‐phenylindol‐2‐yl)phosphane; bis(dibenzylideneacetone)-palladium(0); N-Methyldicyclohexylamine / N,N-dimethyl-formamide

2: iodine; silver trifluoroacetate / chloroform

3: lithium diisopropyl amide / tetrahydrofuran / -78 °C

4: toluene-4-sulfonic acid / acetonitrile

5: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / dimethyl sulfoxide

6: hydrogen; palladium on activated charcoal; acetic acid

7: potassium tri-sec-butyl-borohydride / tetrahydrofuran / -78 °C

8: Resolution of racemate

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; N-Methyldicyclohexylamine; palladium on activated charcoal; hydrogen; iodine; potassium acetate; silver trifluoroacetate; potassium tri-sec-butyl-borohydride; toluene-4-sulfonic acid; acetic acid; bis(dibenzylideneacetone)-palladium⁽⁰⁾; lithium diisopropyl amide; di‐tert‐butyl‐(1‐phenylindol‐2‐yl)phosphane; In tetrahydrofuran; chloroform; dimethyl sulfoxide; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/cb501013w

Reference yield:

: C₄₁H₄₈BIO₈

: 33606-81-4,32630-90-3
(-)-aR-11R-myricanol

: 181228-75-1,32630-90-3
Myricanol

Guidance literature:: Multi-step reaction with 5 steps

1: toluene-4-sulfonic acid / acetonitrile

2: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / dimethyl sulfoxide

3: hydrogen; palladium on activated charcoal; acetic acid

4: potassium tri-sec-butyl-borohydride / tetrahydrofuran / -78 °C

5: Resolution of racemate

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; palladium on activated charcoal; hydrogen; potassium acetate; potassium tri-sec-butyl-borohydride; toluene-4-sulfonic acid; acetic acid; In tetrahydrofuran; dimethyl sulfoxide; acetonitrile;
DOI:10.1021/cb501013w