BrC₆H₄CB₁₀H₁₀CC₆H₄C₁₀H₇N₂

Base Information

• Chemical Name: BrC₆H₄CB₁₀H₁₀CC₆H₄C₁₀H₇N₂
• CAS No.: 894106-06-0
• Molecular Formula: C₂₄H₂₅B₁₀BrN₂
• Molecular Weight: 529.49
• Mol file: 894106-06-0.mol

Synonyms:

Chemical Property of BrC₆H₄CB₁₀H₁₀CC₆H₄C₁₀H₇N₂

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of BrC₆H₄CB₁₀H₁₀CC₆H₄C₁₀H₇N₂

There total 1 articles about BrC₆H₄CB₁₀H₁₀CC₆H₄C₁₀H₇N₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 10.0%

5-trimethylstannyl-2,2′-bipyridine (894106-12-8) + BrC6H4CB10H10CC6H4Br (894106-05-9) → BrC6H4CB10H10CC6H4C10H7N2 (894106-06-0) + N2C10H7C6H4CB10H10CC6H4C10H7N2 (894106-07-1)

Guidance literature:

tetrakis(triphenylphosphine) palladium⁽⁰⁾; In m-xylene; preparative tlc on alumina (cyclohexane-EtOAc-Et3N 100:2:1);

DOI:10.1021/ic060327m

Reference yield:

cis-dichlorobis(2,2′-bipyridine)ruthenium(II) (345911-20-8,19542-80-4,158060-65-2,34795-02-3,15746-57-3) + BrC6H4CB10H10CC6H4C10H7N2 (894106-06-0) → BrC6H4CB10H10CC6H4C10H7N2(Ru(N2C10H8)2)(2+)*2PF6(1-)=(BrC6H4CB10H10CC6H4C10H7N2(Ru(N2C10H8)2))(PF6)2

Guidance literature:

In methanol; chloroform; refluxing in MeOH-CHCl3 (1:1); size-exclusion chromy. (Sephadex LH20, MeOH);

DOI:10.1021/ic060327m

upstream raw materials:

5-trimethylstannyl-2,2′-bipyridine

BrC₆H₄CB₁₀H₁₀CC₆H₄Br