methyl 4-((1'-iodoferrocenyl)ethynyl)benzoate

Base Information

Chemical Name:methyl 4-((1'-iodoferrocenyl)ethynyl)benzoate
CAS No.:1295581-57-5
Molecular Formula:C₂₀H₁₅FeIO₂
Molecular Weight:470.089
Hs Code.:

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Chemical Property of methyl 4-((1'-iodoferrocenyl)ethynyl)benzoate

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Technology Process of methyl 4-((1'-iodoferrocenyl)ethynyl)benzoate

There total 1 articles about methyl 4-((1'-iodoferrocenyl)ethynyl)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 31869-01-9
1-ethynyl-1'-iodoferrocene

: 619-44-3
methyl 4-iodobenzoate

: 1295581-57-5
methyl 4-((1'-iodoferrocenyl)ethynyl)benzoate

Guidance literature:: bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; In tetrahydrofuran; Schlenk techniques used under N2, Pd(Ph3P)2Cl2 (0.028 mmol) and CuI (0.058 mmol) added to deoxygenated soln. of 8 (2.85 mmol) and 9 (2.79 mmol) in THF/diisopropylamine (4:1, v/v), heated at 60°C for 60 h; cooled to room temp., solvent removed under vac., redissolved in CH2Cl2,filtered through silica gel column, chromd. (petroleum ether/CH2Cl2 (4: 1); silica gel); mass-spectrum;
DOI:10.1016/j.jorganchem.2010.12.032

Reference yield: 56.0%

: 1295581-57-5
methyl 4-((1'-iodoferrocenyl)ethynyl)benzoate

: 1066-54-2
trimethylsilylacetylene

: 1295581-59-7
methyl 4-(((1'-(trimethylsilyl)ethynyl)ferrocenyl)ethynyl)benzoate

Guidance literature:: bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; In tetrahydrofuran; Schlenk techniques used under N2, Pd(Ph3P)2Cl2 (0.008 mmol), CuI (0.016 mmol) and HCCSi(CH3)3 (0.899 mmol) added to stirred soln. of 10 (0.422 mmol) in THF/diisopropylamine (1:1, v/v) and stirred for 30 min at 4°C, heated at 50°C for 36 h; cooled to room temp., solvent removed under vac., redissolved in CH2Cl2,filtered through silica gel column, chromd. (petroleum ether/CH2Cl2 (5: 1); silica gel); elem. anal.;
DOI:10.1016/j.jorganchem.2010.12.032