(RS,RS)-1,2-diphenyl-1,2-disupersilyldisilan

Base Information

• Chemical Name: (RS,RS)-1,2-diphenyl-1,2-disupersilyldisilan
• CAS No.: 283163-02-0
• Molecular Formula: C₃₆H₆₆Si₄
• Molecular Weight: 611.262
• Mol file: 283163-02-0.mol

Synonyms:

Chemical Property of (RS,RS)-1,2-diphenyl-1,2-disupersilyldisilan

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (RS,RS)-1,2-diphenyl-1,2-disupersilyldisilan

There total 7 articles about (RS,RS)-1,2-diphenyl-1,2-disupersilyldisilan which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Dichlorphenylsupersilylsilan (283163-09-7) → 1,2-Diphenyl-1,2-disupersilyldisilan (283163-02-0)

Guidance literature:

With sodium naphthalenide; In 1,2-dimethoxyethane; at 25 ℃;

DOI:10.1515/znb-2000-0510

Reference yield:

1-Chlor-1,2-diphenyl-1,2-disupersilyldisilan (283163-04-2) → 1,2-Diphenyl-1,2-disupersilyldisilan (283163-02-0)

Guidance literature:

With sodium naphthalenide; In tetrahydrofuran; at 20 ℃;

DOI:10.1515/znb-2000-0510

Reference yield:

Chlorphenylsupersilylsilan (283163-01-9) → (RS,RS)-1,2-diphenyl-1,2-disupersilyldisilan (283163-02-0) + (meso)-1,2-diphenyl-1,2-disupersilyldisilan

Guidance literature:

Chlorphenylsupersilylsilan; With sodium tri-tert-butylsilanide; In tetrahydrofuran; at -78 - 20 ℃;

With lithium aluminium tetrahydride; In tetrahydrofuran; at 120 ℃; for 2.5h; Title compound not separated from byproducts;

DOI:10.1016/S0022-328X(00)00442-3

upstream raw materials:

Chlorphenylsupersilylsilan

Dichlorphenylsupersilylsilan

1-Chlor-1,2-diphenyl-1,2-disupersilyldisilan

Downstream raw materials:

Phenylsupersilylsilan

Refernces

• 1、 Wiberg, Nils,Niedermayer, Wolfgang. "Supersilylsilanes R*SiX3: Conversion into Disilanes R*X2Si-SiX2R*, Silylenes R*XSi, Cyclosilanes (R*XSi)n, Disilenes R*XSi=SiXR*, Tetrasupersilyl-tetrahedro-tetrasilane [1]". . p. 406 - 416. Retrieved 2007/10/03.