[Yb(3,5-Bu(t)2-2-(OH)-C₆H₂CH=N-8-C₉H₆N(-H))(OC₆H₃(tert-butyl)2)2]

Base Information

• Chemical Name: [Yb(3,5-Bu(t)2-2-(OH)-C₆H₂CH=N-8-C₉H₆N(-H))(OC₆H₃(tert-butyl)2)2]
• CAS No.: 1017241-41-6
• Molecular Formula: C₅₂H₆₉N₂O₃Yb
• Molecular Weight: 943.171
• Mol file: 1017241-41-6.mol

Synonyms:

Chemical Property of [Yb(3,5-Bu(t)2-2-(OH)-C₆H₂CH=N-8-C₉H₆N(-H))(OC₆H₃(tert-butyl)2)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Yb(3,5-Bu(t)2-2-(OH)-C₆H₂CH=N-8-C₉H₆N(-H))(OC₆H₃(tert-butyl)2)2]

There total 2 articles about [Yb(3,5-Bu(t)2-2-(OH)-C₆H₂CH=N-8-C₉H₆N(-H))(OC₆H₃(tert-butyl)2)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

Yb(3+)*3OC6H3(C4H9)2(1-)=Yb(OC6H3(C4H9)2)3 + 2,4-di(tert-butyl)-6-((quinoline-8-ylimino)methyl)phenol → [Yb(3,5-Bu(t)2-2-(OH)-C6H2CH=N-8-C9H6N(-H))(OC6H3(tert-butyl)2)2] (1017241-41-6)

Guidance literature:

In tetrahydrofuran; toluene; (Ar); Yb-compound added dropwise in toluene to THF soln. of organic ligand; stirred for 12 h at room temp.; concd. in vacuum; left for 4 days at room temp.; elem. anal.;

DOI:10.1016/j.poly.2007.10.025

Reference yield: 60.0%

[(3,5-Bu(t)2-2-(OH)-C6H2CH=N-8-C9H6N(-H))YbCl2(DME)] (1017241-38-1) + 2,6-di-tert-butylphenolate, sodium salt (7175-96-4) → [Yb(3,5-Bu(t)2-2-(OH)-C6H2CH=N-8-C9H6N(-H))(OC6H3(tert-butyl)2)2] (1017241-41-6)

Guidance literature:

In tetrahydrofuran; (Ar); THF soln. of Na-compound added to THF soln. of 0.5 equiv. Yb-complex; stirred overnight at room temp.; volatiles removed in vacuum; extracted with toluene; removed by precipitation; elem. anal.;

DOI:10.1016/j.poly.2007.10.025

upstream raw materials:

[(3,5-Bu(t)2-2-(OH)-C₆H₂CH=N-8-C₉H₆N(-H))YbCl₂(DME)]

2,6-di-tert-butylphenolate, sodium salt