(E)-1,1,3-triphenyl-2-trimethylstannylallyl alcohol

Base Information

Chemical Name:(E)-1,1,3-triphenyl-2-trimethylstannylallyl alcohol
CAS No.:97538-07-3
Molecular Formula:C₂₄H₂₆OSn
Molecular Weight:449.18
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (E)-1,1,3-triphenyl-2-trimethylstannylallyl alcohol

Chemical Property:

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Technology Process of (E)-1,1,3-triphenyl-2-trimethylstannylallyl alcohol

There total 2 articles about (E)-1,1,3-triphenyl-2-trimethylstannylallyl alcohol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 97537-75-2,87673-44-7
(1-trimethylstannyl-2-phenyl)vinyllithium

: 97538-07-3,87673-48-1
(E)-1,1,3-triphenyl-2-trimethylstannylallyl alcohol

Guidance literature:: With benzophenone; In tetrahydrofuran; to freshly prepd. soln. of Li-Sn compd. at -78°C was added the carbonyl compd., react. was complete when mixt. became colorless; after hydrolytic work-up solvent was removed to leave cryst. product; recrystn. from hexane; elem. anal.;
DOI:10.1016/0022-328X(85)87105-9

Reference yield:

: 78338-47-3
C₆H₅CHC(Sn(CH₃)3)2

: 97538-07-3,87673-48-1
(E)-1,1,3-triphenyl-2-trimethylstannylallyl alcohol

Guidance literature:: With benzophenone; methyllithium; In tetrahydrofuran; byproducts: tetramethyltin; MeLi in THF was added slowly with stirring at -78°C under Ar to a soln. of PhCH=C(SnMe3)2 in THF, stirred for 1 h, Ph2CO was added at -78°C, mixt. was kept 1 h at -78°C; the reaction mixt. was slowly hydrolyzed by the addn. of water, allowed to warm to room temp., org. layer was sepd., aq. layer extd. with ether, combined org. phases were dried over MgSO4, evapd., residue was recrystd. from hexane; elem. anal.;
DOI:10.1016/0022-328X(83)80057-6