((E)-Styryl)-selenocarbamic acid Se-phenyl ester

Base Information

• Chemical Name: ((E)-Styryl)-selenocarbamic acid Se-phenyl ester
• CAS No.: 153469-65-9
• Molecular Formula: C₁₅H₁₃NOSe
• Molecular Weight: 302.234
• Mol file: 153469-65-9.mol

Synonyms:

Chemical Property of ((E)-Styryl)-selenocarbamic acid Se-phenyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ((E)-Styryl)-selenocarbamic acid Se-phenyl ester

There total 1 articles about ((E)-Styryl)-selenocarbamic acid Se-phenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(E)-1-isocyanato-2-phenylethene (33066-20-5) + Benzeneselenol (645-96-5) → ((E)-Styryl)-selenocarbamic acid Se-phenyl ester (153469-65-9)

Guidance literature:

With potassium tert-butylate; In tetrahydrofuran; Yield given; Ambient temperature;

DOI:10.1039/c39930001760

Reference yield: 7.0%

((E)-Styryl)-selenocarbamic acid Se-phenyl ester (153469-65-9) → Demethoxytuberin (90289-81-9) + (Z)-Demethoxytuberin

Guidance literature:

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In benzene; Heating;

DOI:10.1039/c39930001760

Reference yield:

((E)-Styryl)-selenocarbamic acid Se-phenyl ester (153469-65-9) → (E)-2-Phenylvinyl Isocyanide (41003-97-8)

Guidance literature:

Multi-step reaction with 2 steps

1: 65 percent / Bu₃SnH, azoisobutyronitrile / benzene / Heating

2: 65 percent / Tf₂O, i-Pr₂NEt / CH₂Cl₂ / -78 °C

With 2,2'-azobis(isobutyronitrile); trifluoromethylsulfonic anhydride; tri-n-butyl-tin hydride; N-ethyl-N,N-diisopropylamine; In dichloromethane; benzene;

DOI:10.1039/c39930001760

upstream raw materials:

(E)-1-isocyanato-2-phenylethene

Benzeneselenol

Downstream raw materials:

Demethoxytuberin

(E)-2-Phenylvinyl Isocyanide