tris(tributylstannylmethyl)phenylgermane

Base Information

• Chemical Name: tris(tributylstannylmethyl)phenylgermane
• CAS No.: 862062-13-3
• Molecular Formula: C₄₅H₉₂GeSn₃
• Molecular Weight: 1061.95
• Mol file: 862062-13-3.mol

Synonyms:

Chemical Property of tris(tributylstannylmethyl)phenylgermane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of tris(tributylstannylmethyl)phenylgermane

There total 1 articles about tris(tributylstannylmethyl)phenylgermane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

phenyltris(phenylthiomethyl)germane (862061-11-8) + tributyltin chloride (1461-22-9) → tris(tributylstannylmethyl)phenylgermane (862062-13-3)

Guidance literature:

With (tBu-C₆H₄C₆H₄-tBu)Li; In tetrahydrofuran; byproducts: LiSPh, tBu-C6H4C6H5-tBu, LiCl; all manipulations under oxygen-free and dried Ar atm.; soln. of Ge compd. cooled to -60°C and added to freshly prepared soln. of Li compd., stirred for 6 h at -50°C, Bu3SnCl added at -78°C, warmed to room temp.; solvent evapd. in vac., extd. with hexane, filtered, solvent evapd., purified by Kugelrohr distn.; elem. anal.;

DOI:10.1515/znb-2004-11-1230

upstream raw materials:

phenyltris(phenylthiomethyl)germane

tributyltin chloride