[ReOCl(η3-OCH2C5H3NCH2S)(PPh3)]

Base Information

Chemical Name:[ReOCl(η3-OCH2C5H3NCH2S)(PPh3)]
CAS No.:311319-38-7
Molecular Formula:C₂₅H₂₂ClNO₂PReS
Molecular Weight:653.155
Hs Code.:

Synonyms:

Suppliers and Price of [ReOCl(η3-OCH2C5H3NCH2S)(PPh3)]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [ReOCl(η3-OCH2C5H3NCH2S)(PPh3)]

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [ReOCl(η3-OCH2C5H3NCH2S)(PPh3)]

There total 1 articles about [ReOCl(η3-OCH2C5H3NCH2S)(PPh3)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: [ReOCl₃(PPh₃)₂]

: 37962-41-7
pyridine-2-methanethio-6-methanol

: 311319-38-7
[ReOCl(η3-OCH2C5H3NCH2S)(PPh3)]

Guidance literature:: In chloroform; a mixt. in CHCl3 was refluxed, cooled to room temp.; washed with H2O, the organic layer was dried over Na2SO4, reduced in vol., chromd. on silica gel column (CHCl3 to acetone); elem. anal.;
DOI:10.1016/S0020-1693(00)00209-7

Reference yield: 64.0%

: 311319-38-7
[ReOCl(η3-OCH2C5H3NCH2S)(PPh3)]

: 6258-66-8
(4-chlorophenyl)methanethiol

: [ReO(η3-OCH2C5H3NCH2S)(η1-C6H4Cl-4-CH2S)]

Guidance literature:: With (C₂H₅)3N; In acetonitrile; to a refluxing soln. of complex in CH3CN was added dropwise a soln. of benzenethiol in CH3CN, Et3N was added, stirred under reflux for 45 min; evapd. to dryness, flash chromy. (CHCl3, acetone-CHCl3); elem. anal.;
DOI:10.1016/S0020-1693(00)00209-7

Reference yield: 57.0%

: 311319-38-7
[ReOCl(η3-OCH2C5H3NCH2S)(PPh3)]

: 15894-04-9
(4-fluorophenyl)methanethiol

: [ReO(η3-OCH2C5H3NCH2S)(η1-C6H4F-4-CH2S)]

Guidance literature:: With (C₂H₅)3N; In acetonitrile; to a refluxing soln. of complex in CH3CN was added dropwise a soln. of benzenethiol in CH3CN, Et3N was added, stirred under reflux for 45 min; evapd. to dryness, flash chromy. (CHCl3, acetone-CHCl3); elem. anal.;
DOI:10.1016/S0020-1693(00)00209-7