(S,R)-(+)-{2,3-(1,1'-binaphthyl-2,2'-diyldimethylene)cyclopenta-1,3-dienyl}carbonyl(triphenylphosphine)acetyliron

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Chemical Name:(S,R)-(+)-{2,3-(1,1'-binaphthyl-2,2'-diyldimethylene)cyclopenta-1,3-dienyl}carbonyl(triphenylphosphine)acetyliron
CAS No.:138332-59-9
Molecular Formula:C₄₈H₃₇FeO₂P
Molecular Weight:732.641
Hs Code.:

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Chemical Property of (S,R)-(+)-{2,3-(1,1'-binaphthyl-2,2'-diyldimethylene)cyclopenta-1,3-dienyl}carbonyl(triphenylphosphine)acetyliron

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Technology Process of (S,R)-(+)-{2,3-(1,1'-binaphthyl-2,2'-diyldimethylene)cyclopenta-1,3-dienyl}carbonyl(triphenylphosphine)acetyliron

There total 1 articles about (S,R)-(+)-{2,3-(1,1'-binaphthyl-2,2'-diyldimethylene)cyclopenta-1,3-dienyl}carbonyl(triphenylphosphine)acetyliron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 138259-99-1
((C₁₀H₆)2(CH₂)2C₅H₃)Fe(CO)2CH₃

: 138259-98-0
(S,S)-(+)-{2,3-(1,1'-binaphthyl-2,2'-diyldimethylene)cyclopenta-1,3-dienyl}carbonyl(triphenylphosphine)acetyliron

: 138332-59-9
(S,R)-(+)-{2,3-(1,1'-binaphthyl-2,2'-diyldimethylene)cyclopenta-1,3-dienyl}carbonyl(triphenylphosphine)acetyliron

Guidance literature:: With triphenyl phosphine; (NH₄)2Ce(NO₃)6; C₁₀H₈Na; In acetonitrile; addn. of Ce-nitrate in CH3CN to Fe-complex in CH3CN (-40°C, via syringe), deep green soln., 10 min at -40°C, addn. of PPh3 in CH3CN (via syringe), stirred (10 min, -40°C), addn. of C10H8Na in THF, stirred (10 min, -40°C); quenched (-40°C), partitioned between H2O and CH2Cl2, organic layers dried (Na2SO4), concn., chromy. (alumina(I), hexane and hexane/CH2Cl2, then CH2Cl2 or CH3CN), thin layer chromy. (SiO2, CH2Cl2/petroleum ether 7:3); total yield 41%;
DOI:10.1021/om00038a076