acetylacetonato(4-(2'-(bis[3-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)phenyl]phosphanyl)-[1.1']-(R)-binaphthalenyl-2-yloxy)-3,5-dioxa-4-phosphacyclohepta[2,1-a;3,4-a']-(S)-dinaphthalene)rhodium(I)

Base Information

• Chemical Name: acetylacetonato(4-(2'-(bis[3-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)phenyl]phosphanyl)-[1.1']-(R)-binaphthalenyl-2-yloxy)-3,5-dioxa-4-phosphacyclohepta[2,1-a;3,4-a']-(S)-dinaphthalene)rhodium(I)
• CAS No.: 250697-28-0
• Molecular Formula: C₅H₇O₂*C₆₈H₄₀F₂₆O₃P₂*Rh
• Molecular Weight: 1662.98
• Mol file: 250697-28-0.mol

Synonyms:

Chemical Property of acetylacetonato(4-(2'-(bis[3-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)phenyl]phosphanyl)-[1.1']-(R)-binaphthalenyl-2-yloxy)-3,5-dioxa-4-phosphacyclohepta[2,1-a;3,4-a']-(S)-dinaphthalene)rhodium(I)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of acetylacetonato(4-(2'-(bis[3-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)phenyl]phosphanyl)-[1.1']-(R)-binaphthalenyl-2-yloxy)-3,5-dioxa-4-phosphacyclohepta[2,1-a;3,4-a']-(S)-dinaphthalene)rhodium(I)

There total 1 articles about acetylacetonato(4-(2'-(bis[3-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)phenyl]phosphanyl)-[1.1']-(R)-binaphthalenyl-2-yloxy)-3,5-dioxa-4-phosphacyclohepta[2,1-a;3,4-a']-(S)-dinaphthalene)rhodium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

acetylacetonatodicarbonylrhodium(l) + 4-(2'-(bis[3-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)phenyl]phosphanyl)-[1.1']-(R)-binaphthalenyl-2-yloxy)-3,5-dioxa-4-phosphacyclohepta[2,1-a;3,4-a']-(S)-dinaphthalene (250701-73-6) → acetylacetonato(4-(2'-(bis[3-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)phenyl]phosphanyl)-[1.1']-(R)-binaphthalenyl-2-yloxy)-3,5-dioxa-4-phosphacyclohepta[2,1-a;3,4-a']-(S)-dinaphthalene)rhodium(I) (250697-28-0)

Guidance literature:

In tetrahydrofuran; under Ar, standard Schlenk techniques; precooled soln. of ligand in THF added to soln. of Rh complex (molar ratio 1:1) in THF at -78°C; 30 min at -78°C; warmed slowly to room temp.; stirred for 60 min; concd.; pentane added; ppt. collected; washed with pentane;

DOI:10.1016/S0022-328X(00)00778-6

upstream raw materials:

4-(2'-(bis[3-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)phenyl]phosphanyl)-[1.1']-(R)-binaphthalenyl-2-yloxy)-3,5-dioxa-4-phosphacyclohepta[2,1-a;3,4-a']-(S)-dinaphthalene