(3α,4β,7β,9α,10α,11aα)-7-<<(1,1-dimethylethyl)diphenylsilyl>oxy>-2,3,3a,4,7,8,9,10,11,11a-decahydro-4-(4-methoxyphenoxy)-10-methyl-10-(phenylthio)-6,9-epoxycyclodecafuran-11-one

Base Information

• Chemical Name: (3α,4β,7β,9α,10α,11aα)-7-<<(1,1-dimethylethyl)diphenylsilyl>oxy>-2,3,3a,4,7,8,9,10,11,11a-decahydro-4-(4-methoxyphenoxy)-10-methyl-10-(phenylthio)-6,9-epoxycyclodecafuran-11-one
• CAS No.: 142041-49-4
• Molecular Formula: C₄₂H₄₆O₆SSi
• Molecular Weight: 706.975

Synonyms:

Chemical Property of (3α,4β,7β,9α,10α,11aα)-7-<<(1,1-dimethylethyl)diphenylsilyl>oxy>-2,3,3a,4,7,8,9,10,11,11a-decahydro-4-(4-methoxyphenoxy)-10-methyl-10-(phenylthio)-6,9-epoxycyclodecafuran-11-one

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

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Useful:

Technology Process of (3α,4β,7β,9α,10α,11aα)-7-<<(1,1-dimethylethyl)diphenylsilyl>oxy>-2,3,3a,4,7,8,9,10,11,11a-decahydro-4-(4-methoxyphenoxy)-10-methyl-10-(phenylthio)-6,9-epoxycyclodecafuran-11-one

There total 15 articles about (3α,4β,7β,9α,10α,11aα)-7-<<(1,1-dimethylethyl)diphenylsilyl>oxy>-2,3,3a,4,7,8,9,10,11,11a-decahydro-4-(4-methoxyphenoxy)-10-methyl-10-(phenylthio)-6,9-epoxycyclodecafuran-11-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

(1Z,2-endo,3-exo,6-endo)-6-<<(1,1-dimethylethyl)diphenylsilyl>oxy>-2-(4,5-dihydro-2-furanyl)-1-<2-(4-methoxyphenoxy)ethenyl>-3-methyl-3-(phenylthio)-7-oxabicyclo<2.2.1>heptan-2-ol (142041-48-3,142184-12-1) → (3aα,4α,7β,9α,10α,11aβ)-7-<<(1,1-dimethylethyl)diphenylsilyl>oxy>-2,3,3a,4,7,8,9,10,11,11a-decahydro-4-(4-methoxyphenoxy)-10-methyl-10-(phenylthio)-6,9-epoxycyclodecafuran-11-one (142041-49-4,142129-66-6,142129-69-9)

Guidance literature:

With potassium carbonate; In decalin; for 1h; Heating;

DOI:10.1021/jo00042a036

Reference yield: 19.0%

(1E,2-endo,3-exo,6-endo)-6-<<(1,1-dimethylethyl)diphenylsilyl>oxy>-2-(4,5-dihydro-2-furanyl)-1-<2-(4-methoxyphenoxy)ethenyl>-3-methyl-3-(phenylthio)-7-oxabicyclo<2.2.1>heptan-2-ol (142041-48-3,142184-12-1) → (3aα,4β,7β,9α,10α,11aβ)-7-<<(1,1-dimethylethyl)diphenylsilyl>oxy>-2,3,3a,4,7,8,9,10,11,11a-decahydro-4-(4-methoxyphenoxy)-10-methyl-10-(phenylthio)-6,9-epoxycyclodecafuran-11-one (142041-49-4,142129-66-6,142129-69-9) + (3α,4β,7β,9α,10α,11aα)-7-<<(1,1-dimethylethyl)diphenylsilyl>oxy>-2,3,3a,4,7,8,9,10,11,11a-decahydro-4-(4-methoxyphenoxy)-10-methyl-10-(phenylthio)-6,9-epoxycyclodecafuran-11-one (142041-49-4,142129-66-6,142129-69-9)

Guidance literature:

With potassium carbonate; In toluene; for 5h;

DOI:10.1021/jo00042a036

Reference yield: 19.0%

(1E,2-endo,3-exo,6-endo)-6-<<(1,1-dimethylethyl)diphenylsilyl>oxy>-2-(4,5-dihydro-2-furanyl)-1-<2-(4-methoxyphenoxy)ethenyl>-3-methyl-3-(phenylthio)-7-oxabicyclo<2.2.1>heptan-2-ol (142041-48-3,142184-12-1) → (3aα,4β,7β,9α,10α,11aβ)-7-<<(1,1-dimethylethyl)diphenylsilyl>oxy>-2,3,3a,4,7,8,9,10,11,11a-decahydro-4-(4-methoxyphenoxy)-10-methyl-10-(phenylthio)-6,9-epoxycyclodecafuran-11-one (142041-49-4,142129-66-6,142129-69-9) + (3α,4β,7β,9α,10α,11aα)-7-<<(1,1-dimethylethyl)diphenylsilyl>oxy>-2,3,3a,4,7,8,9,10,11,11a-decahydro-4-(4-methoxyphenoxy)-10-methyl-10-(phenylthio)-6,9-epoxycyclodecafuran-11-one (142041-49-4,142129-66-6,142129-69-9)

Guidance literature:

With potassium carbonate; In toluene; for 5h;

DOI:10.1021/jo00042a036

upstream raw materials:

(1Z,2-endo,3-exo,6-endo)-6-<<(1,1-dimethylethyl)diphenylsilyl>oxy>-2-(4,5-dihydro-2-furanyl)-1-<2-(4-methoxyphenoxy)ethenyl>-3-methyl-3-(phenylthio)-7-oxabicyclo<2.2.1>heptan-2-ol

(1Z,3-endo,6-endo)-6-<<(1,1-dimethylethyl)dimethylsilyl>oxy>-1-<2-(4-methoxyphenoxy)ethenyl>-3-methyl-7-oxabicyclo<2.2.1>heptan-2-one

(1Z,2-endo,3-exo,6-endo)-2-(4,5-dihydro-2-furanyl)-1-<2-(4-methoxyphenoxy)ethenyl>-3-methyl-3-(phenylthio)-7-oxabicyclo<2.2.1>heptane-2,6-diol

(1Z,3-exo,6-endo)-6-<<(1,1-dimethylethyl)dimethylsilyl>oxy>-1-<2-(4-methoxyphenoxy)ethenyl>-3-methyl-3-(phenylthio)-7-oxabicyclo<2.2.1>heptan-2-one

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