IrCC(CH₃)3PHC₆H₁₁(CO)(P(C₆H₅)3)2⁽¹⁺⁾*OSO₂CF₃^(1-)=IrCC(CH₃)3PHC₆H₁₁(CO)(P(C₆H₅)3)2OSO₂CF₃

Base Information

• Chemical Name: IrCC(CH₃)3PHC₆H₁₁(CO)(P(C₆H₅)3)2⁽¹⁺⁾*OSO₂CF₃^(1-)=IrCC(CH₃)3PHC₆H₁₁(CO)(P(C₆H₅)3)2OSO₂CF₃
• CAS No.: 652143-37-8
• Molecular Formula: CF₃O₃S*C₄₈H₅₁IrOP₃
• Molecular Weight: 1078.14
• Mol file: 652143-37-8.mol

Synonyms:

Chemical Property of IrCC(CH₃)3PHC₆H₁₁(CO)(P(C₆H₅)3)2⁽¹⁺⁾*OSO₂CF₃^(1-)=IrCC(CH₃)3PHC₆H₁₁(CO)(P(C₆H₅)3)2OSO₂CF₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of IrCC(CH₃)3PHC₆H₁₁(CO)(P(C₆H₅)3)2⁽¹⁺⁾*OSO₂CF₃^(1-)=IrCC(CH₃)3PHC₆H₁₁(CO)(P(C₆H₅)3)2OSO₂CF₃

There total 1 articles about IrCC(CH₃)3PHC₆H₁₁(CO)(P(C₆H₅)3)2⁽¹⁺⁾*OSO₂CF₃^(1-)=IrCC(CH₃)3PHC₆H₁₁(CO)(P(C₆H₅)3)2OSO₂CF₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

[Ir(=C((t)Bu)P(Cy))(CO)(PPh3)2] + trifluorormethanesulfonic acid (1493-13-6) → IrCC(CH3)3PHC6H11(CO)(P(C6H5)3)2(1+)*OSO2CF3(1-)=IrCC(CH3)3PHC6H11(CO)(P(C6H5)3)2OSO2CF3 (652143-37-8)

Guidance literature:

In diethyl ether; (Ar or N2); addn. of a soln. of acid in Et2O to a soln. of iridium complex in Et2O at -78°C over 5 min, warming to room temp., stirring for 4 h; evapn., washing with hexane, dissolving in CH2Cl2, layering with hexane overnight;

DOI:10.1039/b304076n

upstream raw materials:

trifluorormethanesulfonic acid